نتایج جستجو برای: 2 oxo n

تعداد نتایج: 3136692  

2013
Shi Chunjuan Yang Zhao

In the title compound, C13H22N2O2, both the six-membered ring and the seven-membered lactam ring adopt chair conformations. In the crystal, mol-ecules are linked by pairs of N-H⋯O hydrogen bonds between inversion-related lactam rings into centrosymmetric dimers with an R 2 (2)(8) graph-set motif. Further N-H⋯O hydrogen bonds link the molecules into [100] chains.

Journal: :Molecules 2009
Radoslav Flasík Henrieta Stankovicová Anton Gáplovský Jana Donovalová

Novel coumarin derivatives, 2-oxo-2H-chromenecarbaldehyde hydrazones were prepared by reaction of substituted 2-oxo-2H-chromenecarbaldehydes with N-aminoimides in ethanol in the presence of 4-toluenesulfonic acid as catalyst. The photochromic and thermochromic properties of the prepared compounds were investigated.

Journal: :Journal of the American Chemical Society 2006
Trenton H Parsell Rachel K Behan Michael T Green Michael P Hendrich A S Borovik

Manganese-oxo complexes have long been investigated because of their proposed roles in biological and chemical catalysis. However, there are few examples of monomeric complexes with terminal oxo ligands, especially those with oxomanganese(IV) units. A oxomanganese(IV) complex has been prepared from [MnIIIH3buea(O)]2- ([H3buea]3-, tris[(N'-tert-butylureaylato)-N-ethylene]aminato), a monomeric Mn...

Journal: :Zeitschrift für Kristallographie - New Crystal Structures 2016

Journal: :Journal of the American Chemical Society 2006
Trevor W Hayton James M Boncella Brian L Scott Enrique R Batista

Addition of B(C6H5)3.H2O to U(NtBu)2I2(THF)2 provides U(NtBu)(O)I2(THF)2, a complex with a trans arrangement of the oxo and imido ligands. A DFT study on the Ph3PO adduct, U(NtBu)(O)I2(Ph3PO)2, reveals that there are six bonding orbitals in the O=U=N interaction, much like the bis(imido) N=U=N interaction. However, the calculations suggest that the multiple bonding in the oxo imido complexes is...

2008
Manoj Trivedi Daya Shankar Pandey Nigam P. Rath

In the title compound, [Mo(C(5)H(4)NO(2))(2)O(2)], the Mo(VI) atom exhibits a distorted octa-hedral coordination geometry formed by two terminal oxo ligands and two monoanionic O,O-bidentate pyridinone ligands. The two terminal oxo ligands lie in a cis arrangement, the ketonic O atoms of the pyridinone ligands are coordinated trans to the oxo ligands and the deprotonated hydroxyl O atoms are lo...

2010
Sladjana B. Novaković Bojana M. Drašković Ljiljana S. Vojinović-Ješić Valerija I. Češljević Vukadin M. Leovac

The asymmetric unit of the title compound, (C(12)H(18)N(3)O(4))(2)[ZnCl(4)]·CH(3)OH, consists of two Girard reagent-based cations, a tetra-chlorido-zincate anion and a mol-ecule of methanol as solvate. These components are inter-connected in the crystal structure by an extensive network of O-H⋯O, N-H⋯O, C-H⋯O, O-H⋯N, O-H⋯Cl, N-H⋯Cl and C-H⋯Cl hydrogen bonds. The shortest inter-molecular inter-a...

2014
B. Narayana Prakash S. Nayak Balladka K. Sarojini Jerry P. Jasinski

In the title compound, C13H13NO4, the N-C(=O) bond length of 1.354 (2) Å is indicative of amide-type resonance. The dihedral angle between the mean planes of the benzene ring and oxo-amine group is 36.4 (3)°, while the mean plane of the 2-methyl-idene group is inclined by 84.2 (01)° from that of the oxo-amine group. In the crystal, classical O-H⋯O hydrogen bonds formed by the carb-oxy-lic acid ...

نمودار تعداد نتایج جستجو در هر سال

با کلیک روی نمودار نتایج را به سال انتشار فیلتر کنید