In this article, simple, convenient synthesis of 2-aryl-1- arylmethyl-1H-1,3-benzimidazole (1,2-disubstituted benzimidazoles) via condensation of 1,2-phenylenediamine and aromatic aldehydes using SBA-Pr-SO3H as a nanoporous solid acid catalyst in green protocol was reported.

Carbon dots (CDs) were prepared from p -phenylenediamine, modified with trifluoroacetic acid, and dispersed in a fluoropolymer (FP) film. Unmodified CDs did not disperse well the FP film, resulting concentration quenching; whereas surface modification improved affinity between FP, homogeneous dispersion an photoluminescence quantum yield.

an efficient one-pot oxidation/condensation tandem process has been developed for the synthesis of 2-substituted benzimidazole derivatives from benzylic alcohols and 1,2-phenylenediamine with use of urea-hydrogen peroxide/silica phosphoric acid  as a bifunctional catalyst. this method provides a rapid and efficient access to 2-substituted benzimidazoles.