نتایج جستجو برای: β azido alcohols

تعداد نتایج: 190437  

Journal: :Chemistry 2015
M Victoria Jiménez Javier Fernández-Tornos F Javier Modrego Jesús J Pérez-Torrente Luis A Oro

The borrowing hydrogen methodology allows for the use of alcohols as alkylating agents for CC bond forming processes offering significant environmental benefits over traditional approaches. Iridium(I)-cyclooctadiene complexes having a NHC ligand with a O- or N-functionalised wingtip efficiently catalysed the oxidation and β-alkylation of secondary alcohols with primary alcohols in the presence...

Journal: :Organic & biomolecular chemistry 2015
Jipan Yu Chang Gao Zhixuan Song Haijun Yang Hua Fu

β-Alkoxy sulfides are widely used as versatile building blocks in organic synthesis. Therefore, it is highly desirable to develop a convenient and efficient method for oxysulfenylation of alkenes. In this communication, an easy and efficient metal-free approach to β-alkoxy sulfides has been developed. The protocol uses readily available 1-(arylthio)pyrrolidine-2,5-diones and alcohols as the oxy...

Journal: :Antimicrobial agents and chemotherapy 2015
Aparajita Chatterjee Giulia Bandini Edwin Motari John Samuelson

Enteric protozoan parasites, which are spread by the fecal-oral route, are important causes of diarrhea (Giardia duodenalis) and amebic dysentery (Entamoeba histolytica). Cyst walls of Giardia and Entamoeba have a single layer composed of fibrils of β-1,3-linked GalNAc and β-1,4-linked GlcNAc (chitin), respectively. The goal here was to determine whether hand sanitizers that contain ethanol or ...

2016
Rita Megyesi Enikő Forró Ferenc Fülöp

Many alkaloids containing a tetrahydro-β-carboline skeleton have well-known therapeutic effects, leading to increased interest in the synthesis of these natural products. Enantiomers of N-Boc-protected 1-hydroxymethyl-1,2,3,4-tetrahydro-β-carboline [(±)-7], 1-hydroxymethyl-6-methoxy-1,2,3,4-tetrahydro-β-carboline [(±)-8], and 1-hydroxymethyl-6-fluoro-1,2,3,4-tetrahydro-β-carboline [(±)-9] were ...

2012
Katja Fauster Markus Hartl Tobias Santner Michaela Aigner Christoph Kreutz Klaus Bister Eric Ennifar Ronald Micura

Chemical modification can significantly enrich the structural and functional repertoire of ribonucleic acids and endow them with new outstanding properties. Here, we report the syntheses of novel 2'-azido cytidine and 2'-azido guanosine building blocks and demonstrate their efficient site-specific incorporation into RNA by mastering the synthetic challenge of using phosphoramidite chemistry in ...

Journal: :journal of medicinal plants and by-products 0

the effects of mandarin scions on peel components and juice quality parameters were investigated in this study. peel flavor components were extracted by using cold-press and eluted by using n-hexane. then all analyzed by gc-fid and gc-ms. total soluble solids, total acids, ph value, ascorbic acid as well as density and ash were determined in juice obtained from mandarin scions. twenty-seven, tw...

Journal: :Journal of the American Chemical Society 2013
Kevin Chung Steven M Banik Antonio G De Crisci David M Pearson Timothy R Blake Johan V Olsson Andrew J Ingram Richard N Zare Robert M Waymouth

The regio- and chemoselective oxidation of unprotected vicinal polyols with [(neocuproine)Pd(OAc)]2(OTf)2 (1) (neocuproine = 2,9-dimethyl-1,10-phenanthroline) occurs readily under mild reaction conditions to generate α-hydroxy ketones. The oxidation of vicinal diols is both faster and more selective than the oxidation of primary and secondary alcohols; vicinal 1,2-diols are oxidized selectively...

2013
Zhengzhi Zhang Wei Wang Wanlong Li

Cuticular wax composition greatly impacts plant responses to dehydration. Two parallel pathways exist in Triticeae for manipulating wax composition: the acyl elongation, reduction, and decarbonylation pathway that is active at the vegetative stage and yields primary alcohols and alkanes, and the β-diketone pathway that predominates at the reproductive stage and synthesizes β-diketones. Variatio...

Journal: :Organic & biomolecular chemistry 2012
Weiliang Xu Yonggui Zhou Ruimin Wang Guotao Wu Ping Chen

Lithium amidoborane (LiNH(2)BH(3), LiAB for short), is capable of chemoselectively reducing α,β-unsaturated ketones to the corresponding allylic alcohols at ambient temperature. A mechanistic study shows that the reduction is via a double hydrogen transfer process. The protic H(N) and hydridic H(B) in amidoborane add to the O and C sites of the carbonyl group, respectively.

Journal: :Chemical communications 2014
Balaram S Takale Shanqiang Wang Xuan Zhang Xiujuan Feng Xiaoqiang Yu Tienan Jin Ming Bao Yoshinori Yamamoto

The remarkable effect of an unsupported nanoporous gold catalyst (AuNPore) on chemoselective hydrogenation of α,β-unsaturated aldehydes using silane has been described. Enals can be reduced with excellent selectivity, giving the corresponding allylic alcohols in good to high chemical yields.

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