primary mgcl2.3.3etoh adduct (pct1) was prepared by melt quenching method and then submitted into a programmed thermal dealcoholation project using a fluidized bed reactor. during thermal dealcoholation program, different mgcl2.netoh support samples with n= 3.0, 2.7, 2.4, and 2.1 were selected and named as pct2 to pct5, respectively. structural analysis of the support samples showed a significa...

Activity limiting agents (ALA) are used to avoid thermal runaway during the gas phase polymerization of propylene.

SiO2/MgCl2 (ethoxide type)/TiCl4 Ziegler-Natta catalysts for use in ethylene polymerization and ethylene/1-hexene copolymerization have been prepared using silica with a supported layer of magnesium ethoxide (Mg(OEt)2) as a catalyst precursor, followed by treating with TiCl4 at different Ti/Mg molar ratios, which showed significant effects on the active centers and pore structures of the cataly...

Several types of hybrid catalysts are made through mixing of 4th generation Ziegler-Natta (ZN) and (2-PhInd)2ZrCl2  metallocene catalysts using triethylaluminum (TEA) as coupling agent. Response surface methodology (RSM) is used to evaluate the interactive effects of different parameters including amounts of metallocene and TEA and temperature on metallocene loading. Analyzing the amounts of Al...