We report the rapid amorphization of the prototypical substituted zeolitic imidazolate framework, ZIF-8, by ball-milling. The resultant amorphous ZIF-8 (a(m)ZIF-8) possesses a continuous random network (CRN) topology with a higher density and a lower porosity than its crystalline counterpart. A decrease in thermal stability upon amorphization is also evident.

The first time-resolved in situ X-ray diffraction studies of the hydrothermal crystallisation of open-framework zinc phosphates reveal a pathway of sequential crystallisation involving formation of a metastable low dimensional chain phase before the growth of three-dimensional zeolitic architectures.

The introduction of a triazole-based ligand to the zeolitic imidazolate framework-7 via a postsynthetic ligand exchange strategy not only maintains its framework, high stability and morphology, but also provides extra uncoordinated nitrogen atoms to improve the π-π and Lewis acid-base interactions.

Four organic amine-based solvents were discovered which enable direct exfoliation of graphite to produce high-quality and oxygen-free graphene nanosheets. These solvents outperform previously used solvents and additives such as N-methyl-pyrrolidone and surfactants in terms of their dispersing capacity. The resulting dispersions allow the facile fabrication of zeolitic imidazolate framework (ZIF...

Mixed matrix membranes (MMMs) have gained much interest in the last two decades to be used as water, waste and gas separation membranes. MMMs combine polymer inorganic filler improve performances of pure polymeric However, choice should conducted carefully avoid formation microvoids that can decrease membrane’s performances. Hence, this study synthesis characterization Zeolitic Imidazolate Fram...

Carbamazepine (CBZ) is the most frequently detected pharmaceutical residues in aquatic environments effluent by wastewater treatment plants. Batch and column experiments were conducted to evaluate removal of CBZ from ultra-pure water plant (WWTP) using raw zeolitic tuff (RZT) surfactant modified zeolite (SMZ). Point zero net charge (pHpzc), X-ray diffraction (XRD), fluorescence (XRF), Fourier T...

The U.S. Department of Energy (DOE) is actively investigating the technical feasibility of permanent disposal of high-level nuclear waste in a repository to be situated in the unsaturated zone (UZ) at Yucca Mountain (YM), Nevada. In this study we investigate, by means of numerical simulation, the transport of radioactive colloids under ambient conditions from the potential repository horizon to...

Current article describes application of zeolites in fluid catalytic cracking (FCC). The use of several zeolitic additives for the production light olefins and reduction of pollutants is described. Application of zeolites as fluid catalytic cracking (FCC) catalysts and additives due to the presence of active acid sites in the zeolite framework  increase the formation of desired cracking product...