The mechanical behaviour of unsaturated soils is one of the challenging topics in the field of geotechnical engineering. The use of finite element technique is considered as a promising method to solve settlement and heave problems, as associated with unsaturated soil. Nevertheless, the success of the numerical analysis is strongly dependent on constitutive model being used. The well-known Barc...

The efficiency and stereoselectivity of the conjugate addition of lithium (Z)- or (E)-beta-amino ester enolates, generated by lithium amide conjugate addition to an alpha,beta-unsaturated ester or deprotonation of a beta-amino ester, respectively, to a range of alpha,beta-unsaturated acceptors has been investigated. Deprotonation of a beta-amino ester with LDA, followed by conjugate addition to...

The formation of long chain unsaturated fatty acids from the corresponding saturated acids in animals was established by the work of Schoenheimer and Rittenberg (1) and Stetten and Schoenheimer (2). Recent studies in this laboratory have shown that in yeast the formation of Ag-unsaturated fatty acids is catalyzed by an enzyme system acting on the coenzyme A derivatives of the corresponding satu...

Vascular diseases are the most prominent cause of death, and inflammation and vascular dysfunction are key initiators of the pathophysiology of vascular disease. Lipid peroxidation products, such as acrolein and other α, β-unsaturated aldehydes, have been implicated as mediators of inflammation and vascular dysfunction. α, β-Unsaturated aldehydes are toxic because of their high reactivity with ...

With the goal of developing a modular approach leading to different indoline alkaloid natural-product-like tricyclic derivatives having an unsaturated lactam (see compounds 13, 14, and 16), an aminoindoline-based bicyclic scaffold 10 was obtained from 9. The selective deprotection of the indoline NTeoc or benzylic NHAlloc in compound 10, followed by N-acryloylation and then subjection to a ring...

This paper presents an overview of constitutive modelling of unsaturated soils and the numerical algorithms for solving the associated boundary value problems. It first discusses alternative stress and strain variables that can be used in constitutive models for unsaturated soils. The paper then discusses the key issues in unsaturated soil modelling and how these issues can be incorporated into...

autism spectrum disorder (asd) is a mental condition, present from early childhood, characterized by great difficulty in communicating and forming relationships with others and using language. in the last four decades many studies have shown that immune responses in different regions of brain play an important role in asd pathogenicity. a conservative estimate based on the research suggests tha...

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in this study, both the presence and concentration of some unsaturated compounds in hexane extracts of different parts of anthemis talyschensis showing absorption at wavelength 280-450 nm were surveyed, with the view of possibly using extracts of this plant in new formulations of sunscreen creams. the hexane extracts of flower, leaf and stem of a. talyschensis , collected from northwest iran, w...

one of the common methods to cure unsaturated polyester resins is to use dual initiators. in order to produce an appropriate composite, it is necessary to know the effect of dual initiators on curing behavior. in this paper the effect of benzoyl peroxide, bpo, and tertiary butyl perbenzoate, tbpb, and their mixtures on thermal curing of an unsaturated polyester resin have been investigated. bpo...