A series of lithium complexes were prepared from 2(N-piperazinyl-N'-methyl)-2-methylene-4-R'-6-R-phenols ([ONN](RR')) and characterized through elemental analysis, (1)H and (13)C{(1)H} NMR spectroscopy, and X-ray crystallography. Treatment of the ligands with n-butyllithium afforded {Li[ONN](RR')}(3) [R = Me, R' = (t)Bu, (1); R = R' = (t)Bu (2); R = R' = (t)Am, (3), (t)Am = C(CH(3))(2)CH(2)CH(3...

High-performance photocatalysts have considerable potential to address energy and environmental issues. In this study, dodecylbenzenesulfonate (DBS) modified ZnCuCo layered double hydroxide (DBS-ZnCuCo LDH) microspheres were synthesized through the facile template-free hydrothermal method. Subsequently, mixed-metal oxides (MMOs) with morphological features of DBS LDH, enhanced surface area, inc...

The introduction of dopant concentrations Pt into supported AuPd nanoparticles, when used in conjunction with an evolved unspecific peroxygenase (UPO) from Agrocybe aegerita (PaDa-I) is demonstrated to offer high efficacy towards the one-pot selective oxidation cyclohexane KA oil (cyclohexanol and cyclohexanone), via in-situ synthesis H2O2. optimised AuPdPt/TiO2/PaDa-I system achieves significa...

Copper(I) complexes of a new participative triphosphane ligand (2H) have been prepared and structurally characterized: in particular, [Cu(2H)I] [Cu(2)]2. Hydrogenation the latter species afforded trimetallic hydride [Cu3(2)2(μ-H)] or, presence BEt3, [Cu(2H)(HBEt3)]. Their formation evidences transient [Cu(2H)H] formed by hydrogenolysis Cu–N bond [Cu(2H)(HBEt3)] behaves like complex inserts CO2 ...