A highly enantioselective transformation catalyzed by chiral (acyclic diaminocarbene)gold(I) complexes is reported. The enantioselective synthesis of 2-substituted chromenyl pivalates from racemic phenol-substituted propargyl pivalates was developed. Rearrangement of the substrates in the presence of cationic gold gave allene intermediates, whose cyclization resulted in formation of enantioenri...

The identification of orientation relationships (ORs) plays a crucial role in the understanding of solid phase transformations. In steels, the most common models of ORs are the ones by Nishiyama-Wassermann (NW) and Kurdjumov-Sachs (KS). The defining feature of these and other OR models is the matching of directions and planes in the parent face-centred cubic γ phase to ones in the product body-...

In this paper, we present a comparison of two implementations of our proposed MDA approach for managing variability in a software product line. The implementations correspond to two representative frameworks based on the Model Driven Engineering (MDE) principles. These frameworks are the Graphical Modeling Framework (GMF) and the Generic Model Environment (GME). We built the core assets of the ...

Large quantities of cephalosporins have entered into aquatic environment in recent years, posing potential adverse effect to human health and ecological safety. In this study, cefazolin, one of widely used cephalosporins, was targeted to explore its transformation behaviors in chlorination disinfection process. With the help of ultra high performance liquid chromatography and high resolution ma...

Model-driven engineering is a wide-spread paradigm in modern software engineering. During the last couple of years, many tools and languages have been developed, which are especially designed for model transformations — a discipline which is needed in many model-driven engineering approaches. While most of the existing model-to-model tools and languages are tailored towards batch transformation...

For naturally competent microorganisms, such as Helicobacter pylori, the steps that permit recombination of exogenous DNA are not fully understood. Immediately downstream of an H. pylori gene (dprA) that facilitates high-frequency natural transformation is HP0334 (dprB), annotated to be a putative Holliday junction resolvase (HJR). We showed that the HP0334 (dprB) gene product facilitates high-...

We describe how the SgpDec computer algebra package can be used for composing and decomposing permutation groups and transformation semigroups hierarchically by directly constructing substructures of wreath products, the so called cascade products. transformation semigroup, permutation group, wreath product, Krohn-Rhodes Theory

The characteristics of the intermediates in the reaction, between DNA and pneumococcus, that results in genetic transformation are described in so far as they have been characterized. Transformation with DNA isolated from bacteria carrying in addition to genetic markers (32)P as a radioactive label and (2)H and (15)N as density labels has permitted the characterization of the product of recombi...

Structural transformation—the movement of workers from low-productivity to high-productivity activities— is an essential ingredient of inclusive growth. This paper reviews the evidence on why the pace of structural transformation has differed widely across countries in Asia, with a specific focus on the People’s Republic of China, India, and Thailand. It argues that both government failures rel...

To investigate the functional relationship between the ability of the adenovirus-5 E1A oncogene product to transform with its ability to block adipocytic differentiation and induce apoptosis, we expressed E1A in the 3T3 L1 preadipocytic cell line. The results demonstrate a dramatic, quantitative reciprocal regulation of differentiation and several transformation-associated properties in respons...