in this study silver/poly vinyl alcohol (pva) and silver/poly vinyl pyrrolidone (pvp) nanocomposites were prepared via reduction of silver salt by employing dmf (n, n`- dimethyl formamide) as a reducing agent. effects of protective agents such as pva and pvp were also described here. we show that the acidic ph of pvp solution also affects the interaction between protective agents and silver nan...

Recombinant strains of Escherichia coli constitutively expressing toluene-o-xylene monooxygenase (ToMO) of Pseudomonas stutzeri OX1 and toluene o-monooxygenase (TOM) of Burkholderia cepacia G4 were investigated for their ability to oxidize trichloroethylene (TCE), 1,1-dichloroethylene (1,1-DCE), cis-1,2-dichloroethylene (cis-DCE), trans-1,2-dichloroethylene (trans-DCE), vinyl chloride (VC), and...

The Plasmodium falciparum cysteine proteases falcipain-2 and falcipain-3 appear to be required for hemoglobin hydrolysis by intraerythrocytic malaria parasites. Previous studies showed that peptidyl vinyl sulfone inhibitors of falcipain-2 blocked the development of P. falciparum in culture and exerted antimalarial effects in vivo. We now report the structure-activity relationships for inhibitio...

Poly(vinyl alcohol) and poly(vinyl pyrrolidone) were blended and films were obtained by casting method. Glutaraldehyde, hydrochloric acid and lactic acid were added to investigate their effect on mechanical properties, swelling and solubility of the blends with the aim to find a possible material candidate for medium or long term implants. Combination of all three additives (lactic acid, glutar...

From its creation to its disposal, there are environmental and health problems associated with polyvinyl chloride (vinyl), the major component of vinyl flooring. The production of vinyl creates toxic waste that must be dumped or incinerated. Because very little vinyl is recycled, the waste material must also be landfilled or burned. Furthermore, the heavy chlorine content of these materials res...

Functionalized vinyl pinacol boronates suitable for Suzuki cross-coupling reactions are synthesized using ruthenium-catalyzed olefin cross-metathesis of 1-propenyl pinacol boronate and various alkenes, including functionalized and 1,1-disubstituted alkenes. The resultant boronate cross products are stereoselectively transformed into predominantly Z-vinyl bromides and E-vinyl iodides. The vinyl ...

A practical and scalable synthesis of a Fmoc-protected tricyclic dipeptide mimetic (6), that is, a 1,4-diaza-tricyclo-[8.3.0(3,7)]-tridec-8-ene derivative resembling a rigidified di-L-proline in a polyproline type II (PPII) helix conformation, was developed. The strategy is based on a Ru-catalyzed ring-closing metathesis of a dipeptide (4) prepared by PyBOP coupling of cis-5-vinylproline tert-b...

in this paper, absorption spectra of both solution and films of cyano azobenzene polymer are investigated. the analysis of overlapped absorption spectra of polymer, related to trans and cis isomers, shows that the population of cis isomers is higher than trans isomers. it means that, cyano azobenzene molecules have a folded structure in polymer, in thermal equilibrium. presence of cyano molecul...

trans-fatty acids (tfa) are known as a risk factor for coronary artery diseases. trans-11 vaccenic acid [va; 18:1(n-9)], known as the major trans fatty acid in milk fat, is a positional and geometric isomer of oleic acid and a precursor of conjugated linoleic acid (cla) in human . this study was carried out in order to investigate the effect of cis and trans vaccenic acids on expression of intr...

A set of mild processes for the conversion of vinyl cyclopropyl diazo ketones to highly functionalized cycloheptadienones and vinyl cyclopentenones by use of a target-inspired tandem Wolff/Cope rearrangement sequence is described. A divergent reaction course of the vinyl cyclopropyl diazo ketone substrates under sono- or photochemical activation provides good to excellent yields (55-98%) of the...