We use density functional theory to examine structure− activity relationships of small vanadia clusters supported on anatase TiO2(001) and rutile TiO2(110) surfaces. A thermodynamic analysis indicates that the vanadia monomer cluster can be stabilized on the anatase TiO2(001) surface in a catalytically relevant oxygen environment. On the other hand, vanadia clusters tend to aggregate into dimer...

In this paper, we propose a chemically grown titanium oxide (TiO2) on Si to form a heterojunction for photovoltaic devices. The chemically grown TiO2 does not block hole transport. Ultraviolet photoemission spectroscopy was used to study the band alignment. A substantial band offset at the TiO2/Si interface was observed. X-ray photoemission spectroscopy (XPS) revealed that the chemically grown ...

A procedure for the preparation of semiconductor anodes using mixed-metal oxides bound together and protected with a TiO2 nanoglue has been developed and tested in terms of the relative efficiencies of the oxygen evolution (OER), the reactive chlorine species evolution (RCS), and the hydrogen evolution (HER) reactions. The composition of the first anode is a Ti metal substrate coated with IrTaO...

To understand the effect of substrate microstructure on the formation of TiO2 nanotubes, anodic oxidizations of commercially pure titanium subjected to surface mechanical attrition treatment (SMATed-Ti) and unSMATed-Ti in a glycol solution containing NH4F and small amounts of water were investigated. The SMATed-Ti exhibit a nanocrystallized surface layer containing a high density of grain bound...

BACKGROUND Substrate nanoscale topography influences cell proliferation and differentiation through mechanisms that are at present poorly understood. In particular the molecular mechanism through which cells 'sense' and adapt to the substrate and activate specific intracellular signals, influencing cells survival and behavior, remains to be clarified. RESULTS To characterize these processes a...

Owing to its excellent semiconducting and photoelectronic properties, TiO2 has recently attracted a great deal of interest for a large variety of applications. Examples include the use of TiO2 nanoparticles/films as photocatalysts for environment protection, photoelectron mediators for sensors, photosensitizers in light-emitting devices, and solar cells. With the recent development in nanoscien...

This paper reports the synthesis of a new type of Au@TiO2 yolk-shell nanostructures by integrating ion sputtering method with atomic layer deposition (ALD) technique and its applications as visible light-driven photocatalyst and surface-enhanced Raman spectroscopy (SERS) substrate. Both the size and amount of gold nanoparticles confined in TiO2 nanotubes could be facilely controlled via properl...

A compact TiO2 layer (~1.1 μm) prepared by electrostatic spray deposition (ESD) and swift heavy ion beam (SHI) irradiation using oxygen ions onto a fluorinated tin oxide (FTO) conducting substrate showed enhancement of photovoltaic performance in dye-sensitized solar cells (DSSCs). The short circuit current density (Jsc = 12.2 mA cm(-2)) of DSSCs was found to increase significantly when an ESD ...

Nanostructured carbon-doped TiO2 (C-TiO2) thin film was prepared by pulsed laser deposition (PLD) on ITO substrate. Results of X-ray diffraction (XRD) analysis of the thin film showed that the crystal structure of the C-TiO2 was a hybrid of rutile and anatase. Data of X-ray photoelectron spectroscopic (XPS) analysis confirmed the successful incorporation of carbon into TiO2 molecules, which for...

nt matter & 2013 0.1016/j.nanoen.2 thor at: Materia rnia at San Diego 3; fax: +1 858 534 [email protected] (S. J Abstract We report here a successful fabrication of a 3-D photoelectrode configuration having hydrothermally formed TiO2 nanotubes on parallel Ti fins. The Ti fin arrays were assembled by simple and facile spot welding of alternately tall and short Ti foil assembly, which provides signific...