Thermal degradation behavior, exothermic patterns, and kinetic parameters of symmetrically/asymmetrically substituted polysilanes during the kumada thermal rearrangement in temperature range 100–450 °C, were investigated applying thermogravimetric (TGA) differential scanning calorimetric (DSC) techniques. Three kinds polysilanes, viz., Polydimethylsilane (PDMS), Polydiphenylsilane (PDPS) Polyme...