نتایج جستجو برای: thermal rearrangement

تعداد نتایج: 244102  

Journal: :Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology 2014
Sanjeewa N Senadheera Anthony S Evans John P Toscano Richard S Givens

α-Diazo arylketones are well-known substrates for Wolff rearrangement to phenylacetic acids through a ketene intermediate by either thermal or photochemical activation. Likewise, α-substituted p-hydroxyphenacyl (pHP) esters are substrates for photo-Favorskii rearrangements to phenylacetic acids by a different pathway that purportedly involves a cyclopropanone intermediate. In this paper, we sho...

Journal: :Silicon 2022

Thermal degradation behavior, exothermic patterns, and kinetic parameters of symmetrically/asymmetrically substituted polysilanes during the kumada thermal rearrangement in temperature range 100–450 °C, were investigated applying thermogravimetric (TGA) differential scanning calorimetric (DSC) techniques. Three kinds polysilanes, viz., Polydimethylsilane (PDMS), Polydiphenylsilane (PDPS) Polyme...

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