The residues responsible for the pH-dependent stability of the helix formed by the isolated C-peptide (residues 1-13 of ribonuclease A) have been identified by chemical synthesis of analogues and measurement of their helix-forming properties. Each of the residues ionizing between pH 2 and pH 8 has been replaced separately by an uncharged residue. Protonation of Glu-2- is responsible for the sha...

The Department of Economics has one of the highest rates of students’ failures, repetition and withdrawals in the Kwame Nkrumah University of Science and Technology (KNUST), Kumasi. In the 2011/2012 and 2012/2013 academic years 35.8% and 30.6% of the 232 and 301 final year students respectively could not graduate. This concern has been attributed primarily to the low mathematical ability of the...

Chemical synthesis is a versatile technique for fabricating novel nanostructured materials. In the Rieke process, a metal salt is reduced by an alkali in a hydrocarbon solvent to form small, highly reactive particles. Synthesis at an elevated temperature (200'C) increases the as-synthesized particle size and produces higher coercivities and remanence ratios than observed in similar syntheses at...

In a toluene-treated mutant of Escherichia coli K-12 having a temperature-sensitive, conditionally lethal mutation in the structural gene for deoxyribonucleic acid (DNA) ligase, an extensive DNA repair synthesis occurred in X-irradiated cells at the nonpermissive temperature, 42 C. At the permissive temperature, 30 C, nearly normal semiconservative synthesis and limited repair synthesis were ob...

we evaluated the effect of fe/alumina catalyst contained different cadmium contents and two synthesis temperatures on producing carbon nanotubes by chemical vapor deposition of methane as a feedstock.  x-ray powder diffraction (xrd), n2 adsorption-desorption, scanning electron microscopy (sem), transmission electron microscopy (tem), raman spectroscopy and thermogravimetry analysis (tga) were u...

Background and Aims: To evaluate the effect of temperature on wheat streak mosaic virus (WSMV) resistance phenotype, through total protein, phenol, and peroxidase activity in bread wheat, a factorial experiment was conducted using Adl-Cross (resistant) and Marvdasht (susceptible) cultivars. Materials and Methods: Results showed that incubation at 32C changed the gene expression for resistance ...

The literature of olefin metathesis by heterogeneous supported catalysts, both industrial-type supported metal oxides (ReOx/Al2O3, ReOx/(SiO2−Al2O3), MoOx/SiO2, MoOx/Al2O3, MoOx/(SiO2−Al2O3), WOx/SiO2, and WOx/ (SiO2−Al2O3)) and supported organometallic complexes, is comprehensively reviewed. The focus of this Review is supported metal oxide catalysts, but the well-defined supported organometal...

Olefin metathesis is a prevailing method for the construction of organic molecules. Recent advancements in olefin metathesis have focused on stereoselective transformations. Ruthenium olefin metathesis catalysts have had a particularly pronounced impact in the area of stereoselective olefin metathesis. The development of three categories of Z-selective olefin metathesis catalysts has made Z-ole...

Access to electrification in rural areas of East Timor is extremely limited with as few as 5% of rural households connected to electricity. The government of East Timor intends to increase rural access to electricity significantly in the coming decade. The introduction of small PV systems is envisaged for many households in the most remote areas. Several agencies have piloted the introduction o...

Nano-branched rutile TiO2 nanorod arrays were grown on F:SnO2 conductive glass (FTO) by a facile, two-step wet chemical synthesis process at low temperature. The length of the nanobranches was tailored by controlling the growth time, after which CdS quantum dots were deposited on the nano-branched TiO2 arrays using the successive ionic layer adsorption and reaction method to make a photoanode f...