Nucleic acids play important roles in living systems by storing and transferring genetic information and directing protein synthesis. Recently, it was found that nucleic acids can catalyze chemical and biochemical reactions similar to protein enzymes. In addition, they can also serve as drug targets for the treatment of deadly diseases such as AIDS and cancers. As a result, the 3D structure stu...

This work presents a flexible thick-film Bismuth Tellurium/Antimony Tellurium (BiTe/SbTe) thermoelectric generator (TEG) with reduced material resistivity fabricated by screen printing technology. Cold isostatic pressing (CIP) was introduced to lower the resistivity of the printed thermoelectric materials. The Seebeck coefficient (α) and the resistivity (ρ) of printed materials were measured as...

2014 Some aspects of the thermodynamic state of CdTe crystals grown by different zone passing techniques (sealed ingot zone refining technique and THM in tellurium solvent) are considered with regard to the general objective of getting high resistivity crystals. A vapour growth technique, called sublimation THM, which reduces several drawbacks of classical THM using a tellurium solvent, is deve...

Industrial uses of tellurium are limited, and reported cases of tellurium absorption of occupational origin are rare. Two such cases are reported here. Both showed typical signs and symptoms of intoxication; in particular, the stench of sour garlic was noted on breath and from excreta. An unusual feature was the bluish-black discoloration of the webs of the fingers and streaks on the face and n...

Bbstract Recent developments involving polymer-supported metal complexes as catalysts in oxidation reactions, using dioxygen, hydrogen peroxide, alkyl hydroperoxides, hypochlorite anion and iodosobenzene as oxidants are reviewed. binding of dioxygen, and in catalysis, along with the structurally closely related metallo-phthalocyanines, oxidative polymerization catalysed by polymer-supported cop...

A new hydrated yttrium copper tellurite nitrate, yttrium(III) copper(II) bis-[trioxidotellurate(IV)] nitrate trihydrate, has been synthesized hydro-thermally in a Teflon-lined autoclave and structurally determined using synchrotron radiation. The new phase is the first example containing yttrium, copper and tellurium in one structure. Its crystal structure is unique, with relatively strongly bo...

Despite the burgeoning field of uranium-ligand multiple bonds, analogous complexes involving other actinides remain scarce. For thorium, under ambient conditions only a few multiple bonds to carbon, nitrogen, oxygen, sulfur, selenium and tellurium are reported, and no multiple bonds to phosphorus are known, reflecting a general paucity of synthetic methodologies and also problems associated wit...

We report the synthesis and characterisation of a family of diuranium(IV)-m-chalcogenide complexes including a detailed examination of their electronic structures and magnetic behaviours. Treatment of [U(Tren)] [1, Tren 1⁄4 N(CH2CH2NSiPr3)3] with Ph3PS, selenium or tellurium affords the diuranium(IV)-sulfide, selenide, and telluride complexes [{U(Tren)}2(m-E)] (E 1⁄4 S, 2; Se, 5; Te, 6). Comple...

2014 The energies of surface quantum levels of inversion layers in [0001] planes at the surface of tellurium, calculated from Shubnikov de Haas measurements, are compared with theoretical values obtained with the assumption of a triangular surface potential well. In the experimental concentration range, results are explained by the existence of a single sub-band, separated in two levels due to ...