The effects of process parameters on the extraction of Ginkgo biloba L. leaves with supercritical carbon dioxide were investigated. The investigated parameters include particle size (mean particle diameter 0.19, 0.467 and 1.009 mm), solvent flow rate (1.58×10, 3.22×10 and 4.16×10 kg CO2/min) and pressure (100–300 bar), which were obtained by the response surface methodology (RSM) under the foll...

This article presents the fabrication of size-controllable and shape-flexible microcellular high-density polyethylene-stabilized palladium nanoparticles (Pd/m-HDPE) using supercritical foaming, followed by supercritical impregnation. These nanomaterials are investigated for use as heterogeneous hydrogenation catalysts of biphenyls in supercritical carbon dioxide with no significant surface and ...

The use of supercritical fluids as chromatographic mobile phases provides rapid separations with high efficiency, favoring their use in enantioselective separations. Supercritical fluid technology (SFC) is a versatile tool in the purification, enantioseparation and large-scale production of enantiomers of pharmaceuticals over comparable liquid chromatographic methods and is gaining popularity i...

Carbon dioxide can be used in its liquid (near critical) or supercritical fluid state as a replacement for conventional cleaning solvents, reducing the pollution associated with the operations that would otherwise require significant amounts of volatile organic compounds, ozone depleting substances, or hazardous air pollutants. The results of several near critical/supercritical parts cleaning a...

Supercritical Fluid properties are of interest as being significantly different from liquids or gases in the area near the critical temperature, T c , and the critical pressure, P c. The primary physical feature of supercritical fluids in the immediate critical point region is the very pronounced change in density with pressure. Critical region shown for carbon dioxide in terms of Pr and Tr, th...

black nightshade is a weed plant that grows abundantly in most parts of iran. in this study, central composite response surface method to investigate the effect of temperature 35-55 °c and pressures 170-350 bar during the dynamic time of 120 min, the particle size of 150 microns and flow rate of 3 liters per minute on the efficiency of oil extracted from the fruits of black nightshade and optim...

We present the results from a novel experimental apparatus that can image – at the micron scale – fluid displacements at elevated temperatures and pressures. The images are acquired using a micro-CT scanner (Xradia Versa 500) that has been adapted to allow core flood experiments to be conducted in situ, allowing continuous imaging at resolutions down to around 1 μm. A small cylindrical core – a...

enzyme efficiency was investigated in the lipase-catalyzed hydrolysis of canola oil in supercritical carbon dioxide (scco2). immobilized lipase from mucor miehie (lipozyme im) was used as the catalyst and the results showed that enzyme efficiency dropped at high pressures indicating a possible change in enzyme microstructure. therefore, scanning electron microscopy (sem) was used as a supplemen...

Using a continuous flow apparatus, the solubility of tridodecylamine (TDA) in supercritical CO2 (scCO2), have been measured at temperatures of 308, 318, and 328 K in the pressure range of (8-40) MPa and a flow rate of 150 ± 10 mL min. At 308 and 318 K the solubility increases with pressure up to 15 MPa where it reaches a plateau. At 328 K the solubility increases with pressure up to 35 MPa and ...

Thc sterilizing effect of supercritical carben dioxide (SC-CO,) is described as compared with gaseous C02(G-CO,) and liquid CO,(L-CO,). Baker's yeast, ltscherichia eoli, Staphylococcus aure us and eonidia'ofAspergiilus niger were sterilized by treating with SC-CO, at 200 atm and 350C when the water contcnt of each microorganism was 70 .90%, However, dry cells with a water content of 2 .1O% coul...