Steam methane reforming is a major method of hydrogen production. However, this usually suffers from low energy efficiency and high carbon-emission intensity. To solve issue, novel steam-methane-reforming process over Ni-based catalyst in pressurized dual fluidized bed reactor proposed work. A three-dimensional computational fluid dynamics (CFD) model for the complex physicochemical was built t...

Ultra-thin, high performance composite palladium membrane, developed via a novel electroless plating method, was applied to construct a membrane reactor for methane steam reforming reaction, which was investigated under the following working conditions: temperature 723–823 K, pressure 300–900 kPa, gas hourly space velocity (GHSV) 4000–8000 mL g 1 cat h , steam-to-carbon feed ratio (S/C, mol/mol...

We report a hierarchically structured catalyst with steam reforming and hydrodeoxygenation functionalities being deposited in the micropores and macropores, respectively. The catalyst is highly efficient to upgrade the pyrolysis vapors of pine forest product residual, resulting in a dramatically decreased acid content and increased hydrocarbon yield without external H2 supply.

An interesting application of agricultural renewable sources is the employment of ethanol for supplying Molten Carbonate Fuel Cells (MCFCs). For that purpose, ethanol has to be converted into hydrogen by a steam reforming process. MCFCs are particularly suitable for this kind of applications due to their high tolerability to the impurities which are contained into the reaction products and also...

High-power-density alcohol fuel cells can relieve many of the daunting challenges facing a hydrogen energy economy. Here, such fuel cells are achieved using CsH2PO4 as the electrolyte and integrating into the anode chamber a Cu-ZnO/Al2O3 methanol steam-reforming catalyst. The temperature of operation, 250°C, is matched both to the optimal value for fuel cell power output and for reforming. Peak...

Three conventional and novel hydrogen and liquid fuel production schemes, i.e. steam methane reforming (SMR), solar SMR, and hybrid solar-redox processes are investigated in the current study. H2 (and liquid fuel) productivity, energy conversion efficiency, and associated CO2 emissions are evaluated based on a consistent set of process conditions and assumptions. The conventional SMR is estimat...

In this idealized, stoichiometric equation, cellulose (represented as C,H,,O,) reacts with water to produce hydrogen and carbon dioxide, mimicking the commercial manufacture of hydrogen from methane by catalytic steam reforming chemistv. More realistically, a practical technology must be able to convert the cellulose, hemicellulose, lignin, and extractive components of the biomass feedstock to ...

2. Productivity at this level means that the production costs of H 2 (expressed as the cost in US dollars per joule of calorific value contained in the molecule) are two to three times higher than for natural gas 4,5. However, taking into account the transportation and distribution costs of natural gas, and how pure you want the H 2 to be, the comparative cost of H 2 production can vary. Biomas...

The partial oxidation and CO2 reforming of methane were studied on Pt/Al2O3, Pt/ZrO2, and Pt/ Ce–ZrO2 catalysts. The reducibility and the oxygen transfer capacity were evaluated by oxygen storage capacity (OSC). The effect of the support on the cleaning mechanism of the catalyst surface was investigated by the sequence of CH4/O2 and CH4/CO2 pulses. The Pt/Ce–ZrO2 catalyst showed the highest sta...