The equilibrium properties of particle adsorption is investigated theoretically. The model relies on a free-energy formulation which allows us to generalize the Maxwell-Boltzmann description to solutions for which the bulk volume fraction of potentially adsorbed particles is very high. As an application we consider the equilibrium physical adsorption of neutral and charged particles from soluti...

This paper presents the adsorption of crystal violet (CV+) from aqueous solution on surfactant-modified dolomite. Liquid phase batch operations were carried out to observe the effect of various experimental parameters such as initial dye concentration, adsorbent dosage, pH and NaCl concentration. The optimum conditions for these parameters were calculated by Taguchi method. Equilibrium isotherm...

Zirconia powder was synthesized via a sol gel method and placed in a batch reactor for cesium removal investigation. X-ray analysis and Fourier transform infrared spectroscopy were utilized for the evaluation of the developed adsorbent. The adsorption process has been investigated as a function of pH, contact time and temperature. The adsorption is strongly dependent on the pH of the medium whe...

the binding, release and oxidation of oxygen occur at the heme group iron ion. hemoglobinoxidation-reduction studies have been previously performed using spectroelectrochemistry (sec) andhave provided insight into the hemoglobin electron transfer process and more specifically, into theheme group electronic factor and subunit interaction influences. in this study, the number of fullerenecarbon a...

The objective of this work is investigation of the adsorption and decomposition of Reactive Blue 19 from industrial wastewaters using laccase enzyme immobilized on activated carbon powder and fiber as adsorbent. Time, pH, temperature, stirring rate, the amount of the adsorbent, dye initial concentration, solution flow rate in the column and column height were studied as key operating parame...

Thermodynamic equations are de®eloped for adsorption of multicomponent gas mixtures in microporous adsorbents based on the principles of solution thermodynamics. The con®entional spreading pressure and surface area ®ariables, which describe 2-D films, must be abandoned for adsorption in micropores, in which spreading pressure cannot be measured experimentally or calculated from intermolecular f...

We conjecture the exact scaling theory for the adsorption of two-dimensional polymers by using boundary S matrices. We compute the boundary free energy (the “g-function”), study the flow from adsorbed to desorbed phase, and derive the crossover exponent and all the geometrical exponents at the transition. More generally, we solve the special transition in the O(n) model, the polymer case corres...

The polymer translocation into nanopores is generally facilitated by external driving forces, such as electric or hydrodynamic fields, to compensate for entropic restrictions imposed by the confinement. We investigate the dynamics of translocation driven by polymer adsorption to the confining walls that is relevant to chromatographic separation of macromolecules. By using the self-consistent fi...

Expanded graphite nanosheets (EG-nanosheets) were used for adsorption of Malachite Green (MG) from aqueous solution. The influences of dye concentrations, absorbent dosage, pH values and the temperatures on the adsorption were investigated as well. The dye adsorption experiments were carried out by utilizing batch procedure. EG-nanosheets were initially characterized by scanning electron micros...

Expanded graphite nanosheets (EG-nanosheets) were used for adsorption of Malachite Green (MG) from aqueous solution. The influences of dye concentrations, absorbent dosage, pH values and the temperatures on the adsorption were investigated as well. The dye adsorption experiments were carried out by utilizing batch procedure. EG-nanosheets were initially characterized by scanning electron micros...