The direct crystallization of dolomite from an aqueous solution at temperatures between 60–220 °C was followed in situ through time-resolved synchrotron-based energy-dispersive X-ray diffraction combined with offline high-resolution imaging, X-ray diffraction, and infrared spectroscopy. Crystalline CaMg(CO3)2 phases form through a three-stage process. In the first stage, a nanoparticulate magne...

Intending to understand the structural basis of their activity in catalysis, amorphous Na x Ta y O z was monitored by situ X-ray diffraction and total scattering experiments during crystallization a nanocomposite natrotantite perovskite.

The self-assembly of apoferritin molecules into crystals is a suitable model for protein crystallization and aggregation; these processes underlie several biological and biomedical phenomena, as well as for protein and virus self-assembly. We use the atomic force microscope in situ, during the crystallization of apoferritin to visualize and quantify at the molecular level the processes responsi...

When heated to a temperature close to glass transition temperature, metallic glasses (MGs) begin to crystallize. Under deformation or particle irradiation, crystallization occurs at even lower temperatures. Hence, phase instability represents an application limit for MGs. Here, we report that MG membranes of a few nanometers thickness exhibit properties different from their bulk MG counterparts...

Poly(trimethylene terephthalate) nanocomposites containing COOH functionalized multi-walled nanotubes were synthesized with in situ polymerization method. The microstructure of the nanocomposites was studied by SEM, in terms of the dispersion state of the nanotubes and the polymer–nanotube interface. The thermal behaviour, mechanical properties and conductivity of these resultant PTT/MWCNTs nan...

Many mechanical and physical processes are associated with the generation of acoustic waves produced by the rapid release of energy from localized sources within a material. Acquiring and processing these waves allows non-destructive control of phenomena such as the extension of cracks in a structure under stress, plastic deformation, phase transitions, etc. Few works were devoted in past to ac...

We demonstrate the use of covalently modified graphite as a convenient and powerful test-bed for the versatile investigation and control of 2-D crystallization at the liquid solid interface. Grafted aryls act as surface defects and create barriers to supramolecular self-assembly. An easily tunable grafting density allows for varying the effect of such defects on supramolecular self-assembly. Fi...