نتایج جستجو برای: silicon halide

تعداد نتایج: 88191  

Journal: :Biochemistry 1994
C S Yuan S Liu S F Wnuk M J Robins R T Borchardt

S-Adenosylhomocysteine (AdoHcy) hydrolase is irreversibly inactivated by (E)-5',6'-didehydro-6'-deoxy-6'-halohomoadenosines (EDDHHAs, halogen = I, Br, and Cl). The inactivation is concomitant with the reduction of the enzyme-bound NAD+ (E.NAD+) to NADH, the release of halide ion, and the formation of adenine (Ade) from the EDDHHAs. The mechanism of this inactivation involves two catalytic pathw...

2011
Gongke Wang Wen Tang Xiaoxiao Hao Changling Yan Yan Lu

The binding mechanism of the interactions of halide ions (F, Br and I) with bovine serum albumin (BSA) and hemoglobin (Hb) were studied at different temperatures, by using ion-selective electrodes. The experimental data were treated according to Klotz equation, and the number of binding sites and the binding constants were determined. The results show that the binding sites of F on protein mole...

2015
Łukasz Tabisz Ainur Tukibayeva Radoslaw Pankiewicz Marta Dobielska Boguslawa Leska Reza Khodarahmi

Five novel disiloxane compounds comprising guanidinium and pyridinium moieties were obtained with high yields and purity. The verified synthetic pathways were then applied for modification of pre-functionalized silica gel, producing materials with the analogous organic side-chains. These halide-containing compounds and materials were then compared as to their ion-exchange properties: two disilo...

2015
Rajesh Giri

In the present work the effect of different concentration of halide quenchers (Cl, Br, I) on 4-methyl-5-ethoxy-7-methoxy coumarin (1) and 4-methyl-5,7-diethoxy coumarin (2) in aqueous solutions have been carried out at 20 temperature. It was observed that the fluorescence intensity of these coumarin derivatives decrease with increase in the concentration of the quenchers except Cl quencher. Fur...

Journal: :Biochemistry 1993
K H Verschueren J Kingma H J Rozeboom K H Kalk D B Janssen B W Dijkstra

Haloalkane dehalogenase from Xanthobacter autotrophicus GJ10 catalyzes the conversion of 1,2-dichloroethane to 2-chloroethanol and chloride without use of oxygen or cofactors. The active site is situated in an internal cavity, which is accessible from the solvent, even in the crystal. Crystal structures of the dehalogenase enzyme complexed with iodoacetamide, chloroacetamide, iodide, and chlori...

2015
Sergey Khromov Carl Hemmingsson Bo Monemar Lars Hultman Galia Pozina S. Khromov C. Hemmingsson B. Monemar L. Hultman

Journal: :Chemical communications 2013
Liena Qin Hajime Hirao Jianrong Steve Zhou

A regioselective Heck reaction of aliphatic olefins and aryl bromides is realized at internal carbons of olefins. Methanol solvent promoted halide ionization from neutral arylpalladium halide complexes via hydrogen bonding, so as to create cationic aryl-Pd species for regioselective olefin insertion.

2016
Tyler Denniston Saman Amarasinghe Leslie A. Kolodziejski

Many image processing and simulation tasks are naturally expressed as a pipeline of small computational kernels known as stencils. Halide is a popular domainspecific language and compiler designed to implement stencil algorithms. Halide uses simple language constructs to express what to compute and a separate scheduling co-language for expressing how to perform the computation. This approach ha...

Journal: :Nanoscale 2011
Manzhou Zhu Gerentt Chan Huifeng Qian Rongchao Jin

We report some interesting results of the chemical reactivity of thiolate-protected [Au(25)(SCH(2)CH(2)Ph)(18)](0) nanoclusters with two types of salts, including tetraoctylammonium halide (TOAX) and NaX. At the early stage of the reaction, [Au(25)(SCH(2)CH(2)Ph)(18)](0) was found to spontaneously convert to its anionic form ([Au(25)(SCH(2)CH(2)Ph)(18)](-)) in the presence of either type of sal...

2014
Samson Jegan Jennifer Packianathan Thomas Muthiah Duraiswamy Tamilselvi

BACKGROUND Most of the benzyladenine and furfuryladenine derivatives inhibit tumor/cancer cell growth; their toxicity is lesser than the compounds used for the treatment of cancer now-a-days. Many cytokinin derivatives are tested for anticancer activity. RESULTS A series of transition metal complexes containing N(6)-benzyl/furfuryl aminopurines of formula [Mn(FAH)2(H2O)(Cl3)]2.Cl2 (1), [Co(FA...

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