نتایج جستجو برای: sesquiterpene coumarin

تعداد نتایج: 6204  

Journal: :Tobacco control 2003
M Givel

OBJECTIVE This paper examines policy processes regarding why the USA and Norway have not regulated coumarin in tobacco. DESIGN A qualitative analysis of all tobacco industry documents regarding coumarin since the 1950s from the 1998 US Master Settlement Agreement and subsequent legal settlements. Additional data were collected from newspaper reports, general internet search engines, journal a...

Journal: :Chemical science 2017
Alexander G Shtukenberg Qiang Zhu Damien J Carter Leslie Vogt Johannes Hoja Elia Schneider Hongxing Song Boaz Pokroy Iryna Polishchuk Alexandre Tkatchenko Artem R Oganov Andrew L Rohl Mark E Tuckerman Bart Kahr

Coumarin, a simple, commodity chemical isolated from beans in 1820, has, to date, only yielded one solid state structure. Here, we report a rich polymorphism of coumarin grown from the melt. Four new metastable forms were identified and their crystal structures were solved using a combination of computational crystal structure prediction algorithms and X-ray powder diffraction. With five crysta...

Journal: :علوم گیاهان زراعی ایران 0
فرنگیس خیالپرست پردیس کشاورزی و منابع طبیعی دانشگاه تهران، استادیار منیژه سبکدست پردیس کشاورزی و منابع طبیعی دانشگاه تهران، مربی منوچهر کریمی پردیس کشاورزی و منابع طبیعی دانشگاه تهران، کارشناس امین ابراهیمی پردیس کشاورزی و منابع طبیعی دانشگاه تهران، دانشجوی کارشناسی ارشد عبدالرحمن رسول نیا پردیس کشاورزی و منابع طبیعی دانشگاه تهران، کارشناس

durum wheat is one of the most important cereals that culture in the west of iran and dry land from long time. in order to study of chemical stress on germination of iranian durum wheat by coumarin in 5 levels (0, 10, 20, 30, 45 mg/l), an experiment was conducted in randomized complete design as factorial with three replications on 20 iranian durum wheat, which involve two genotypes as control ...

Journal: :Journal of the American Chemical Society 2004
YuRui Zhao Quan Zheng Kenneth Dakin Ke Xu Manuel L Martinez Wen-Hong Li

Photocaged fluorescent molecules are important research tools for tracking molecular dynamics with high spatiotemporal resolution in biological systems. We have designed and synthesized a new class of caged coumarin fluorophores. These coumarin cages displayed more than 200-fold fluorescence enhancement after UV photolysis. Remarkably, the uncaging cross section of a 1-(2-nitrophenyl)ethyl (NPE...

2011
Divyesh Patel Premlata Kumari Navin Patel

A series of novel thiazolidinones have been synthesized by reaction of various Schiff bases of coumarin with thioglycolic acid. The reaction of 4-hydroxy coumarin with POCl3 yielded 4chloro coumarin 2 and 4-chloro-3, 4', 3', 4"-tercoumarin 2a. Compound 2 was reacted with pphenylene diamine to yield 4-[(4-aminophenyl)amino]-2H-chromen-2-one.Various Schiff bases of coumarin were synthesized by co...

2017
Ni Made Dwi Sandhiutami Moordiani Moordiani Dian Ratih Laksmitawati Nurul Fauziah Maesaroh Maesaroh Wahyu Widowati

OBJECTIVES Inflammation is an immune response toward injuries. Although inflammation is healing response, but in some condition it will lead to chronic disease such as rheumatoid arthritis, inflammatory bowel disease, atherosclerosis, Alzheimer's and various cancer. Indonesian cassia (Cinnamomum burmannil C. Nees & T. Ness) known to contain coumarin, is widely used for alternative medicine espe...

Journal: :Physical chemistry chemical physics : PCCP 2013
Caroline M Krauter Jens Möhring Tiago Buckup Markus Pernpointner Marcus Motzkus

In the present work we have explored the ultrafast relaxation network of coumarin and umbelliferone (7-hydroxy-coumarin) using time-resolved femtosecond spectroscopy and quantum chemical calculations. Despite the importance of the photophysical properties of coumarin derivatives for applications in biomedicine, the low fluorescence quantum yield of coumarin itself has not been fully understood ...

Journal: :Drug metabolism and disposition: the biological fate of chemicals 2009
Kari E Schlicht Jeannette Zinggeler Berg Sharon E Murphy

Cytochrome P450 2A13-catalyzed alpha-hydroxylation is a critical step in the activation of the tobacco carcinogens 4-(methylnitrosamino)-1-(3-pyridyl)-1-butanone (NNK) and (S)-N'-nitrosonornicotine [(S)-NNN]. In the enzyme's active site, a single polar residue, Asn297, can influence substrate binding, orientation, and metabolism. We determined the effects of N297A mutation on enzyme kinetics an...

Journal: :Biotechnology and bioengineering 2016
Stefan Tippmann Gionata Scalcinati Verena Siewers Jens Nielsen

Terpenes have various applications as fragrances, cosmetics and fuels. One of the most prominent examples is the sesquiterpene farnesene, which can be used as diesel substitute in its hydrogenated form farnesane. Recent metabolic engineering efforts have enabled efficient production of several terpenes in Saccharomyces cerevisiae and Escherichia coli. Plant terpene synthases take on an essentia...

2017
De-Sheng Ker Sze Lei Pang Noor Farhan Othman Sekar Kumaran Ee Fun Tan Thiba Krishnan Kok Gan Chan Roohaida Othman Maizom Hassan Chyan Leong Ng

BACKGROUND Sesquiterpenes are 15-carbon terpenes synthesized by sesquiterpene synthases using farnesyl diphosphate (FPP) as a substrate. Recently, a sesquiterpene synthase gene that encodes a 65 kDa protein was isolated from the aromatic plant Persicaria minor. Here, we report the expression, purification and characterization of recombinant P. minor sesquiterpene synthase protein (PmSTS). Insig...

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