Organic luminogens have been widely used in optoelectronic devices, bioimaging, and sensing. Conventionally, the synthesis of organic requires sophisticated, multistep design, reaction, isolation procedures. Herein, products melt-phase condensation benzoguanamine (BG; 2,4-diamino-6-phenyl-1,3,5-triazine) at 370–410 °C display interesting reaction-condition-dependent luminescence properties, inc...