The metaiodobenzylguanidine (MIBG) radiopharmaceutical, an analogue of norepinephrine, has been used to diagnose certain diseases in the cardiovascular system when radiolabeled with I. This radiopharmaceutical can also be used to treat tumors, such as neuroblastomas and pheochromocytomas, when radiolabeled with I. Its clinical use is often accompanied by a slow intravenous administration, where...

The catalytic activities of SBA-15 aluminosilica meso/macroporous monoliths (Si/Al = 72) and mesoporous powders (Si/Al = 70) have been investigated using batch Friedel–Crafts alkylation of single-ring aromatic compounds, including toluene, ethylbenzene, cumene, and styrene, with benzyl alcohol. The toluene alkylation activities of the meso/macroporous monolith catalysts were compared with nanop...

A protonated polyaniline-functionalized SBA-15 mesoporous silica nanomaterial (H(+)-PANI/SBA-15) with high surface area and ideal surface properties for the adsorption of anionic dyes is synthesized. Compared with the conventional emeraldine salt of polyaniline (H(+)-PANI), H(+)-PANI/SBA-15 has a significantly higher adsorption capacity for the anionic dye Orange G and is a more effective sorbe...

The adsorption and activation of both CO2 methanol are mainly affected by the distance Lewis acid site, Zr4+, base, Zr4+/O2−, Zr-based catalysts. In this paper, Zr-incorporated SBA-15 (Zr-SBA-15) Zr-grafted (Zr/SBA-15) catalysts were prepared with different Zr environments, analyzed N2 adsorption–desorption isotherms, X-ray diffraction, UV-vis spectra, XPS. It was proposed that Zr-SBA-15 cataly...

Tuning the morphological and acidic properties of mesoporous molecular sieve materials is highly valuable for catalyst design towards reactions involving large molecules. In this work, a series Ga-containing SBA-15 ordered (OMMs) were synthesized following acid-free strategy. Ga-SBA-15 exhibits an acid amount 0.48 mmol/g, comparable to Al-SBA-15 (0.45 mmol/g). addition, it found that straight s...

A series of vanadia catalysts supported on SBA-15 (V/SBA) with a vanadia (V) content ranging from 1% to 11% were prepared by an incipient wetness method. Their catalytic behavior in the dehydrogenation of isobutane to isobutene with CO2 was examined. The catalysts were characterized by N2 adsorption, X-ray diffraction (XRD), scanning electron microscopy (SEM), Raman spectroscopy, and temperatur...

INTRODUCTION Confinement of biomolecules in structured nanoporous materials offers several desirable features ranging from chemical and thermal stability, to resistance to degradation from the external environment. A new generation of mesoporous materials presents exciting new possibilities for the formulation and controlled release of biological agents. Such materials address niche application...

We report the preparation of highly ordered mesoporous Fe-Al-SBA-15 with isolated extraframework Fe species under acidic conditions. The materials were characterized by means of UV resonance Raman spectroscopy, in conjunction with BET, XRD, TEM, UV-vis, H2-TPR, FT-IR, and 27Al MAS NMR spectroscopy. The addition of both Fe and Al to the synthesis gel of SBA-15 results in the formation of isolate...