Partial oxidation of methane (POM) is a potential technology to increase the efficiency synthesizing mixture CO and H2 called syngas, in comparison steam reforming processes. Recently, supported metals modified with Re have emerged as active catalysts for POM. However, role this reaction has been unclear. Here, we demonstrate that addition Ru/Al2O3 catalyst changes mechanism. The bimetallic oxi...

Abstract The paper deals with the study of rhenium recovery by AMR anionite from model high-acidic sulfuric solution as well its desorption ammonia in column experiments. Total dynamic exchange capacity was calculated. Experimental data were processed using Thomas, Yoon-Nelson and Bed Depth Service Time models, basic parameters It found that total calculated Thomas fit closest to experimental v...

Hepatocellular carcinoma (HCC) is the most common primary liver tumor and one of the fifth most common tumors worldwide. In this article we report the results of in vivo studies of potential anticancer agent "[188Re] rhenium-ImDendrim" derived from [188Re]rhenium-nitro-imidazole-methyl -1,2,3-triazol-methyl-di-(2-pycolyl)amine as radioactive ligand loaded 5th generation poly-L-lysine denrimer (...

The high-valent oxo-molybdenum(VI) and -rhenium(VII) and -(V) derivatives MoO2Cl2, ReCH3O3 (MTO) and ReIO2(PPh3)2 catalyze the selective hydrogenation of alkynes to alkenes at 80 degrees C under 40 atm of pressure. The reduction of sulfoxides to sulfides has also been performed by oxo-rhenium and -molybdenum complexes using hydrogen as a reducing agent. Activation of hydrogen by MoO2Cl2 and MoO...

Gel-permeation chromatography (GPC) has been used to analyze transition-metal-based squares, triangles, and related supramolecular complexes. Using rhenium-containing molecular squares of different sizes, a linear calibration curve has been established, which was used for confirming the relative sizes of other assemblies. GPC can also discriminate cyclic trimers and tetramers of a dirhodium bui...

a r t i c l e i n f o a b s t r a c t Keywords: Reverse Monte Carlo EXAFS Wavelet analysis Germanium Rhenium trioxide In this work we present the Reverse Monte Carlo (RMC) modeling scheme, designed to probe the local structural and thermal disorder in crystalline materials by fitting the wavelet transform (WT) of the EXAFS signal. Application of the method to the analysis of the Ge K-edge and R...

NaRe$_2$(PO$_4$)$_3$ phosphate-based ceramic with the structure of kosnarite mineral was obtained by spark plasma sintering. Rhenium (Re) served as a chemical and structural analog technetium. The relative density 85%. mechanism Re static leaching from at room temperature investigated. rate rhenium $1.3\times10^{-5}$ g/(cm$^2$*day).

A thermal stress range analysis of tungsten-rhenium thin film thermocouples based on ceramic substrates is presented to analyze the falling off and breakage problems caused by the mismatch of the thermal stresses in thin film thermocouples (TFTCs) and substrate, and nano-indentation experiments are done to measure and calculate the film stress to compare with the simulation results. Optimal des...

Summarization of electronic discussion fora is a unique challenge; techniques that work startlingly well on monolithic documents tend to fare poorly in this informal setting. Additionally, conventional techniques ignore much of the structures that have the potential to serve as valuable features in the summarization task. We present several novel examples of such features, including the catalys...