نتایج جستجو برای: propane oxidative dehydrogenation

تعداد نتایج: 134254  

2008
Surendar R. Venna Moises A. Carreon

Introduction SAPO-34 is a silicoaluminophosphate zeolite with 8-membered ring windows (~0.38nm) displaying chabazite structure. SAPO-34 is an efficient catalyst showing improved catalytic performance in reactions such as methanol conversion to olefins [1], oxidative dehydrogenation of propane [2], conversion of light alkenes [3]. Its catalytic properties are mainly attributed to its mild acidit...

Journal: :The journal of physical chemistry. B 2005
Morris D Argyle Kaidong Chen Enrique Iglesia Alexis T Bell

In situ diffuse reflectance UV-visible spectroscopy was used to measure the dynamics of catalyst reduction and oxidation during propane oxidative dehydrogenation (ODH) on VOx/gamma-Al2O3. Transients in UV-visible intensity in the near-edge region were analyzed using a mechanistic model of ODH reactions. Rate constants per site for the kinetically relevant reduction step (C-H bond activation) me...

Journal: :Angewandte Chemie 2013
Kazuhiko Amakawa Lili Sun Chunsheng Guo Michael Hävecker Pierre Kube Israel E Wachs Soe Lwin Anatoly I Frenkel Anitha Patlolla Klaus Hermann Robert Schlögl Annette Trunschke

Highly dispersed molybdenum oxide supported on mesoporous silica SBA-15 has been prepared by anion exchange resulting in a series of catalysts with changing Mo densities (0.2-2.5 Mo atoms nm(-2) ). X-ray absorption, UV/Vis, Raman, and IR spectroscopy indicate that doubly anchored tetrahedral dioxo MoO4 units are the major surface species at all loadings. Higher reducibility at loadings close to...

2012
Zhen Yan D. Wayne Goodman

Inspired by previous studies on model systems, a series of silica-supported Au–Ni catalysts were prepared and tested for the conversion of propane in the presence of hydrogen. The Au–Ni/SiO2 catalysts were prepared by successive impregnation, i.e. Ni was deposited first followed by Au. TEM/EDX results confirmed the presence of bimetallic Au–Ni nanoparticles. The dehydrogenation of propane to pr...

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