A series of mixed Cp* amidate tantalum complexes Cp*Ta(RNC(O)R')X(3) (where R = Me(2)C(6)H(3), (i)Pr, R' = (t)Bu, Ph, X = Cl, Me) have been prepared via salt metathesis and their fundamental reactivities under reducing conditions have been explored. Reaction of the tantalum chloro precursors with potassium graphite under N(2) or Ar leads to the stereoselective formation of the terminal tantalum...

this study compares the functional capabilities of different metacarpal fixation constructs under physiological loadings in an attempt to identify the optimal construct rather than the strongest one. one hundred and twenty-six preserved human metacarpals were mechanically tested after oblique osteotomies and internal fixation. maximum load to failure, average structural rigidity, and energy abs...

irrigation with distillery effluent, besides influencing crop yield, may have considerable impact on physical properties of soil because of its high salt and organic carbon contents. this experimental study was conducted to evaluate the effect of distillery effluent on hydraulic conductivity of a sandy loam alluvial soil and compare the effect of inorganic salts of potassium (k) with that of di...

nitration of potassium sulphamate was carried out using a mixture of sulphuric and nitric acid at -30 °c. the reaction time was optimized at the mole ratio of sulphuric to nitric acid of (1:3.5). the difference in product yield by changing the potassium to ammonium sulphamate was studied throughly. it was found that both the yield and purity of the product is better starting with potassium sulp...

abstract nitrogen is a key nutrient in plant growth and it is necessary for amino acid synthesis. sulfur has very important role in the biosynthesis of the alliums flavor and pungency precursors and potassium improve crop yield and quality. in order to study the effect of ammonium nitrate and potassium sulfate on concentration some of the mineral elements in onion (allium cepa l. azar shahr cv....

Background: Conventional fixation methods of posterior wall acetabular fractures feature the use of plating and lagscrews. However, fixation of posterior wall fractures with buttress plating alone offers potential advantages by avoidingthe hardware complications related to hardware placement through the wall fragment. The purpose of this study wasto examine if buttress plating...