Water is an effective promoter of the endo-selective opening of trisubstituted epoxides, enabling related cascades leading to a variety of substituted ladder polyether structures. When used in conjunction with a tetrahydropyran-templated nucleophile, water can overcome the powerful electronic directing effect of a methyl substituent at either site of the epoxide, making water a uniquely versati...

Methods: Samples of four polyvinyl siloxanes, one polyether, one polysulfide, and one irreversible hydrocolloid were fabricated with 1.0, 1.5, and 3.5mm-thickness. Three samples of different thickness were placed on the Digora optical plate and exposed. The optical density (pixels) was recorded in three areas resulting in a total of 360 measurements. Data were analyzed by 2-way ANOVA and Tukey ...

The use of iodobenzene diacetate and iodine under photolytic conditions provides and efficient method for the oxidative cyclization of spiroacetals bearing an hydroxyalkyl side chain to bis-spiroacetals. An overview is provided of the use of this reaction for the synthesis of several bis-spiroacetal containing natural products such as the polyether antibiotics salinomycin and CP44,161 and the s...

INTRODUCTION A dental impression is a negative imprint of an oral structure that can be used to produce a positive cast of a patient's teeth as a permanent record. The accuracy of the impression affects the accuracy of the cast, and a precise impression is needed in order to create prosthesis with optimal fitting. Minimization of misfit is an important aim in prosthesis science and dental impla...

Polyether-based polymer electrolytes containing ceramic inorganic oxide fillers often exhibit improved mechanical and ion transport properties compared to their filler-free counterparts. The nature of local scale interactions that give rise to these enhanced properties is explored by nuclear magnetic resonance measurements.

Maduramicin ls a polyether carboxylic ionophore produced by the prokaryotic Gram-positive bacterium Actinomadura yumaensis (formerly classified incorrectly as Nocardia X-148681)). It is a potent antibiotic with useful activity as a coccidiostat. Maduramicin was discovered and characterlzed independently by two diHbrcnt commercial Iaboratories:Hoffmann-La Roche Inc. designated the compound X-148...

A series of polyurethane elastomers based on an aliphatic diisocyanate and a polyether macroglycol was polymerized with various cross-link densities and OH/NCO ratios. Stoichiometries yielding between 8,600 and 12,900 gm/mole/crosslink and an OH/NCO ratio of 1.1 resulted in polymers with the low modulus, yet high strength and elongation necessary for maxillofacial applications.

A new type of materials, the backbone-thermoresponsive hyperbranched polyether, was successfully synthesized by proton-transfer polymerization of 1,4-butanediol diglycidyl ether and various triols, and the lower critical solution temperature (LCST) values can be readily adjusted from 19.0 to 40.3 degrees C by changing the hydrophilic/hydrophobic balance of BDE and triols.