Water purification is of extreme importance worldwide. p-Nitrophenol was used as a test chemical to design and test an organoclay for the removal of p-nitrophenol from an aqueous solution. Synthesis of the organoclay with methyltrioctadecylammonium bromide [CH(3)(CH(2))(17)](3)NBr(CH(3)) labeled as MTOAB results in multiple expansions of the montmorillonite clay from 1.24 nm to a maximum of 5.2...

PURPOSE To evaluate the dimensional accuracy of the resultant (duplicative) casts made from two different impression materials (polyvinyl siloxane and polyether) in parallel and angulated implants. MATERIALS AND METHODS Three definitive master casts (control groups) were fabricated in dental stone with three implants, placed at equi-distance. In first group (control), all three implants were ...

A direct comparison of surface loading, interface shear strength, and interface hydrolytic stability was made between a phosphonate and two siloxane monolayers formed on the native oxide surface of Ti-6Al-4V. Surface loading for the phosphonate was ca. four times greater (on a nanomole/area basis) than for the siloxanes; mechanical strengths per surface-bound molecule were comparable, but the h...

We introduce a siloxane chain-based hydrophobizer that exhibits superior thermal and chemical stability compared to the conventional hydrophobizing silane agent under conditions of over 300 °C and pH 2-13. To demonstrate the capability of the siloxane chain-based hydrophobizer to serve as a highly robust chemical surface modifier, we present two applications: the formation of fine metal nanopar...

In a novel application, infrared spectroscopic ellipsometry is used to provide clear evidence for the formation of a covalent bond at a polymer/polymer interface. Specifically, there is evidence for the formation of a Si-O-C bond resulting from a reaction between the silyl (SiH) group of a poly(hydrogen methyl siloxane) crosslinker used in poly(dimethyl siloxane) and the carboxylic acid group o...

Branched Siloxane Brushes In article number 2301561, King Lun Yeung and co-workers develop a flexible hierarchically branched siloxane brushes by repeated grafting of on TiO2 nanorods. The facilitates water nucleation, while the structure promotes efficient droplet jumping. as-prepared surface displays significant improvement in harvesting at both high low humidity conditions, making it suitabl...