Model-dependence of the single-pion contribution to the GDH, Baldin, and forward spin-polarizability sum rules is explored, using the most recent SAID multipole analysis. Results from SAID and MAID are compared. We have calculated the GDH, Baldin and forward spin-polarizability (γ 0) sum rules using our most recent analysis of single-pion photoproduc-tion data. This set of integrals is useful i...

A series of interaction models for ethylene oxide are developed for use in molecular simulation of the thermal properties of both the gas and liquid phases. While it is possible to develop nonpolarizable models to accurately generate either the gas or liquid properties separately, it was not possible to do so using a single model for both phases. A polarizable, rigid all-atom model was develope...

Based on the semiclassical model of damped oscillators, a procedure is developed for the calculation of the dispersion of refractive index, polarizability, and dielectric permeability, which are treated as complex quantities. Using experimental values of refractive indices and employing the frequencies of strong absorption bands, a least squares fit is used to determine oscillator strengths and...

A new aromaticity definition is advanced as the compactness formulation through the ratio between atoms-in-molecule and orbital molecular facets of the same chemical reactivity property around the pre- and post-bonding stabilization limit, respectively. Geometrical reactivity index of polarizability was assumed as providing the benchmark aromaticity scale, since due to its observable character;...

The static polarizability of cylindrical systems is shown to have a strong dependence on a uniform magnetic field applied parallel to the tube axis. This dependence is demonstrated by performing exact numerical diagonalizations of simple cylinders (rolled square lattices), armchair and zig-zag carbon nanotubes (rolled honeycomb lattices) for different electron-fillings. At low temperature, the ...

A bridge type microwave Fourier transform spectrometer, equipped with flat oversized Stark cells and an operational range from 8 GHz to 40 GHz is described. As application we report the experimental determination of the vibronic ground state dipole moment and of the anisotropy in the static polarizability of 1,1-dideuteroallene. Our experimental values are: /za = 0.0053(2) D for the dipole mome...

This report presents the polarizability matrix of a tri-isotropic sphere. A tri-isotropic material exhibits coupling between electric, magnetic, and in addition, a third kind of material response. Each of these three fields creates three different kind of polarizations. The paper derives the polarizability components of such a sphere in vacuum and makes physical interpretations of the results f...