Abstract A systematic investigation of the hydrogen peroxide oxidation reaction (HPOR) in phosphate buffer (pH = 7.3) on an Au(111) single crystal modified with a 4-mercaptopyridine self-assembled monolayer (SAM) has been conducted before and after metallization Pt. While bare shows considerable electrocatalytic activity towards HPOR, inhibition modification SAM implies that adsorbed molecules ...

The CO preferential oxidation (PrOx) is one of the critical steps in hydrogen production and purification for Polymer Electrolyte Membrane Fuel Cell (PEMFC). This reaction was investigated in the presence of excess hydrogen over Cu/CeO2, Pt/CeO2 and Cu-Pt/CeO2 catalysts. The ceria supports was prepared via precipitation method and Cu-Pt/CeO2 catalyst was synthesized by sequential impregnation o...

Platinum metal catalyzes the reduction of dialkyl(diolefin)platinum(II) complexes by dihydrogen to alkanes and platinum(0). The reaction involves adsorption of the platinum(II) complex on the platinum(0) catalyst surface with conversion of the alkyl moieties to platinum surface alkyls; these appear as alkane products. The platinum atom originally present in the soluble organoplatinum species be...

Applications of polymer electrolyte membrane fuel cells (PEM-FCs) require a continued search for an optimal catalyst with attributes of high activity, durability, low cost, and resistance to negative effects of impurities in the fuel. Platinum-based bimetallic catalyst systems are widely utilized in PEM-FCs because of their good performance in both the cathode and the anode. Alloying with inexp...

gaz-angubin is a sweet exudate naturally produced by an insect from the gavan-e-gaz-angubin plant. adsorption and desorption isotherms for a gaz-angubin sample were determined at 15° and 25°c over a range of relative humidity from 0 to 90% using a dynamic vapor sorption system. at different levels of relative humidity, changes in sample mass were continuously measured versus time and described ...

We detail here a method to integrate chemical synthesis with the formation of nanoscale electrical “sockets” to allow the in situ construction of three-component molecular wires. Reaction chemistry offers molecular materials an overwhelming amount of diversity and functionality and could provide a method for nanoscale electronics to be synthesized rather than fabricated. Though presently underu...

The well-known electrochemical probe Fe(CN)63-/Fe(CN)64- is widely used for estimating the electrochemically active area of electrodes modified with carbon nanotubes, conductive polymers, enzymes, etc. In this study, we platinum electrode, smooth or platinized different roughness factors, to demonstrate that such a redox couple fails respond surface variation. We determined factors Pt surfaces ...

background : the brain is a rare site of metastases from ovarian cancer. limited data are available on prognostic factors, standard treatment, and survival. knowledge of clinical prognostic factors would help the management of patients with brain metastases. the aim of this study is to evaluate the impact of clinical factors and treatment modalities on survival in patients with brain metastases...

We study kinetically controlled orientational and structural transitions of molecular thin films during growth in situ and in real time, using diindenoperylene (DIP) as an example. By time-resolved surface-sensitive x-ray scattering (out of plane and in plane), we follow the organic molecular beam deposition of DIP on silicon oxide, on stepped sapphire, and on rubrene as an organic model surfac...