نتایج جستجو برای: palladated catalyst

تعداد نتایج: 44036  

Journal: :Nano letters 2016
Bunyarat Rungtaweevoranit Jayeon Baek Joyce R Araujo Braulio S Archanjo Kyung Min Choi Omar M Yaghi Gabor A Somorjai

We show that the activity and selectivity of Cu catalyst can be promoted by a Zr-based metal-organic framework (MOF), Zr6O4(OH)4(BDC)6 (BDC = 1,4-benzenedicarboxylate), UiO-66, to have a strong interaction with Zr oxide [Zr6O4(OH)4(-CO2)12] secondary building units (SBUs) of the MOF for CO2 hydrogenation to methanol. These interesting features are achieved by a catalyst composed of 18 nm single...

2015
Laura Pastor-Pérez Tomás Ramírez Reina Svetlana Ivanova Miguel Ángel Centeno José Antonio Odriozola

In this work, the WGS performance of a conventional Ni/CeO2 bulk catalyst is compared to that of a carbon-supported Ni-CeO2 catalyst. The carbon-supported sample resulted to be much more active than the bulk one. The higher activity of the Ni-CeO2/C catalyst is associated to its oxygen storage capacity, a parameter that strongly influences the WGS behavior. The stability of the carbon-supported...

2014
VIPIN KUMAR

Heterogeneous catalysis and their application in industrial-scale organic synthesis of fine chemicals are greatly facilitated by catalysis and further on by catalyst recovery and recycles to fits most “principles of green chemistry. In acid media, terpenoids generally undergoes various transformations. The terpenoid transformations include various liquid Bronsted and Lewis Acids, Acid clays, He...

2016
Myung Lang Yoo Yong Ho Park Young-Kwon Park Sung Hoon Park Jang-Ho Lee Animesh Dutta

Fast catalytic pyrolysis of wild reed was carried out at 500 ̋C. Waste fluidized catalytic cracking (FCC) catalyst disposed from a petroleum refinery process was activated through acetone-washing and calcination and used as catalyst for pyrolysis. In order to evaluate the catalytic activity of waste FCC catalyst, commercial HY zeolite catalyst with a SiO2/Al2O3 ratio of 5.1 was also used. The b...

2009
Peng Yan Huanwang Jing

Four new chiral polymers of BINOLSalen-cobalt ACHTUNGTRENNUNG(III) salt complexes have been designed, synthesized and applied to the direct fabrication of chiral propylene carbonate from racemic propylene oxide. The (R/S)-polymer catalyst 2 and (S/R)-polymer catalyst 4 exhibit better enantioselectivity than the (R/R)-polymer catalyst 1 and the (S/S)-polymer catalyst 3 and have been recovered an...

1999
Pio Forzatti Luca Lietti

The fundamentals of catalyst deactivation are presented in this review. The chemico-physical aspects concerning the various deactivation causes (i.e. poisoning, sintering, coking, solid-state transformation, masking, etc.) have been analyzed and discussed, along with the mathematical description of the deactivation phenomena. # 1999 Elsevier Science B.V. All rights

Journal: :Physical chemistry chemical physics : PCCP 2013
Gabor Samjeské Shin-ichi Nagamatsu Shinobu Takao Kensaku Nagasawa Yoshiaki Imaizumi Oki Sekizawa Takashi Yamamoto Yohei Uemura Tomoya Uruga Yasuhiro Iwasawa

We have prepared and characterized a SnO2-decorated Pt-Sn(oxidized)/C cathode catalyst in a polymer electrolyte fuel cell (PEFC). Oxygen reduction reaction (ORR) performance of Pt/C (TEC10E50E) remained almost unchanged or even tended to reduce in repeated I-V load cycles, whereas the I-V load performance of the Pt-Sn(oxidized)/C prepared by controlled oxidation of a Pt-Sn alloy/C sample with t...

Journal: :international journal of environmental research 2015
j. p. montanez s. gomez l. b. pierella a. n. santiago

photodegradation of dicamba, an ionizable herbicide, using tio2 supported on hzsm-11 zeolite was investigated. four photocatalysts with different weight percentages (wt%) of tio2 were evaluated: 3%, 10%, 30% and 50%. the effects of the catalyst concentration, the initial ph value and the repeatability of the photocatalytic activity after multiple cycles of reuse were also evaluated. results sho...

2011
D. Rosenthal F. Girgsdies O. Timpe G. Weinberg R. Schlögl

CO oxidation over polycrystalline ruthenium dioxide was monitored in an in-situ XRD setup. The evolution of the bulk state of the catalyst was followed by in-situ XRD during reaction, while the surface morphology and chemical state before and after reaction were investigated by HRSEM and EDX. The commercial RuO2 powder was calcined prior reaction to ensure the formation of completely oxidized R...

Journal: :Molecules 2011
Kuen-Song Lin Cheng-Yu Pan Sujan Chowdhury Mu-Ting Tu Wan-Ting Hong Chuin-Tih Yeh

In the present work, a microchannel reactor for autothermal reforming of methanol using a synthesized catalyst porous alumina support-CuO/ZnO mixed with ZrO₂ sol washcoat has been developed and its fine structure and inner surface characterized. Experimentally, CuO/ZnO and alumina support with ZrO₂ sol washcoat catalyst (catalyst slurries) nanoparticles is the catalytically active component of ...

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