نتایج جستجو برای: oxygen containing ligand

تعداد نتایج: 641052  

Aziz Shahrisa Reza Tabrizi

New macrocyclic polyether-diester ligands (3-5) containing the 4H-pyran-4-one subcyclic unit have been prepared by treating various glycols with dimethyl chelidonate (10). In the reaction of compound 10 with ethylene glycol and diethylene glycol, two noncyclic diester and tetraester (6-9) were produced in each case. The new marcocyclic ligand 4 formed stable complexes with benzylammonium pe...

Journal: :Science 2009
Ameen A Salahudeen Joel W Thompson Julio C Ruiz He-Wen Ma Lisa N Kinch Qiming Li Nick V Grishin Richard K Bruick

Cellular iron homeostasis is maintained by the coordinate posttranscriptional regulation of genes responsible for iron uptake, release, use, and storage through the actions of the iron regulatory proteins IRP1 and IRP2. However, the manner in which iron levels are sensed to affect IRP2 activity is poorly understood. We found that an E3 ubiquitin ligase complex containing the FBXL5 protein targe...

Journal: :Nanoscale 2015
David A J Herman Soshan Cheong-Tilley Andrew J McGrath Benjamin F P McVey Matthias Lein Richard D Tilley

The decomposition of organometallic compounds as precursors has revolutionized the synthesis of nanoparticles in solution. However, effective control of size and size distribution of iron nanoparticles has remained challenging due to the high reactivity of iron towards oxygen or oxygen-containing materials. Reported is a decomposition study that shows how metal to ligand bonding and symmetry of...

Journal: :The Journal of biological chemistry 1982
R E White M J Coon

Evidence of several types has accumulated that cytochrome P-450 has a thiolate anion as one of the axial ligands to heme (the fifth ligand). On the other hand, there is as yet no general agreement on the nature of the axial ligand trans to thiolate (the sixth ligand), although nitrogen and oxygen have been proposed. To resolve the controversy, the ligand exchange reactions of cytochrome P-450 w...

Mohammad javad Taghizadeh

Modafinil [2-[(diphenylmethyl)sulfinyl]acetamide] is used clinically in the treatment of narcolepsy and sleeping disorders. The synthesis of modafinil, begins with the reaction of benzhydrol and thioglycolic acid in trifluoroacetic acid to afford benzhydrylsulfinyl acetic acid. The reaction of acid with thionyl chloride in benzene followed by treatment with ammonium hydroxide gave acetamide...

Abolfazl Mohammadzadeh Moghadam Amir Kavussi, Morteza Jalili Qazizadeh, Seyed Ali Ziaee,

This study was conducted in order to evaluate the effects of long term ageing on toughness and resilient modulus of asphalt concrete mixtures containing Electric Arc and Basic Oxygen Furnace steel slags. After initial evaluation of the properties of steel slags using X-ray Diffraction and Scanning Electric Microscope, eleven sets of laboratory mixtures were prepared. Each set was treated replac...

Leila Hassanzadeh Mohammad Ebrahim Eshraghi Mohammad Reza Yaftian,

Phosphoryl containing ligand tri-n-octylphosphine oxide (TOPO) in dichloromethane has been used as an extracting agent for tetravalent thorium and trivalent europium ions from their 1 M sodium nitrates. The equilibrium data reveal that both ions are extracted as the complexes at 1:3 metal/ligand ratio. The values of conditional extraction equilibrium constant (Kex) show the superior extract...

Journal: :Journal of the Metal Finishing Society of Japan 1969

Journal: :Frontiers in Bioengineering and Biotechnology 2019

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