Vertical phase separation of the donor and the acceptor in organic bulk heterojunction solar cells is crucial to improve the exciton dissociation and charge transport efficiencies. This is because whilst the exciton diffusion length is limited, the organic film must be thick enough to absorb sufficient light. However, it is still a challenge to control the phase separation of a binary blend in ...

in fermented products containing bifidobacteria, factors such as organic acid concentration and b-galactosidase activity are important in the development of flavor and texture of final products. both the process conditions and medium components have significant effects on fluctuation of such factors. the effects of whey permeate powder and yeast extract concentrations, as nitrogen sources was i...

liquid membrane processes have attracted many interests in recent years for removal of heavy metals such as cadmium from industrial wastewaters. in this study, a modified hybrid liquid membrane system is introduced. the setup is worked by applying the water-insoluble dioctyl phthalate as the organic solvent. n-octanol and tetra butyl ammonium bromide are added to the organic phase to increase t...

The growth of molecular organic thin films by the process of organic vapor phase deposition (OVPD) was initiated by Professor Steve Forrest OVPD transports organic molecules to a cold substrate by a hot inert carrier gas. It has proven useful for the deposition of organic semiconductors, and is capable of patterned growth with micron resolution. Professors Benziger and Forrest collaborated to e...

Flavin adenine dinucleotide (FAD) is involved in important metabolic reactions where the biological function is intrinsically related to changes in conformation. In the present work, FAD conformational changes were studied in solution and in gas phase by measuring the fluorescence decay time and ion-neutral collision cross sections (CCS, in a trapped ion mobility spectrometer, TIMS) as a functi...

Pseudomonas sp. strain ST-200, which is capable of conversion of cholesterol, was isolated from humus soil. This organism effectively modified cholesterol dissolved in an organic solvent by dehydrogenation and oxygenation. When the organism was grown in a medium overlaid with a 10%/ volume of a mixed organic solvent (p-xylene and diphenylmethane; 3:7, vol/vol) containing cholesterol (20 mg/ml),...

We have developed novel experiments aimed at understanding whether and how quickly organic aerosols (OA) mix using single-particle mass spectrometry, as different treatments of mixing in regional models significantly affect predicted mass and composition. First, we designed experiments that separate OA formation chemistry from thermodynamics to test whether two populations of particles equilibr...

In this study, genetically engineered Pseudomonas putida TODE1 served as a biocatalyst for the bioproduction of valuable 3-methylcatechol (3MC) from toluene in an aqueous-organic two-phase system. The two-phase system was used as an approach to increase the biocatalyst efficiency. Among the organic solvent tested, n-decanol offered several benefits including having the highest partitioning of 3...

L-phenyta}anine methy] ester (Phe-OMe) as substrates was dene mainly in a water-organic one phase solvent system. The organic so]yent content used was less than the saturatien concentration in buffer. With organic solvents with high logP ya]ues, the enzymatic actiyity increased as the organic solyent content increased; but further increases in the organic solvent content decreased the enzymatic...