Chronoamperometric curves for the oxidation of a ferrocenyl derivative via potential step, calculated using Cottrell equation, showed less diffusion-controlled currents on platinum wire electrode. This lower deviation cannot be explained Butler–Volmer heterogeneous kinetics, but was ascribed to negatively capacitive current associated with redox reaction. The in fully oxidized electrical corres...

Understanding the properties of charge dynamics is crucial to many practical applications, such as electrochemical energy devices and transmembrane ion channels. This work proposes a Maxwell–Ampère Nernst–Planck (MANP) framework for description dynamics. The MANP model with curl-free condition on electric displacement shown be dissipative respect convex free-energy functional, demonstrated equi...

Title of Dissertation: SPECIFIC HEAT AND NERNST EFFECT OF ELECTRON-DOPED CUPRATE SUPERCONDUCTORS Hamza Balci, Doctor of Philosophy, 2004 Dissertation directed by: Professor Richard L. Greene Department of Physics This thesis consists of two separate studies on Pr2−xCexCuO4 (PCCO), a member of the electron-doped high temperature cuprate superconductor family: specific heat and the Nernst effect....