Three kinds of inorganic alkali are introduced into tetraethylenepentamine (TEPA)and polyethyleneimine (PEI)-modified MCM-41 as the CO2 adsorbents. FT-IR and TGA are used to characterize the surface groups and the thermal stability of adsorbents. Chemical titration method is used to measure the alkali amounts of adsorbents. Thermo-gravimetric analysis with 10% CO2/90% N2 as the simulated flue g...

The catalytic performance of incorporated V-MCM-41 catalysts for the partial direct oxidation of methane to formaldehyde with molecular oxygen has been investigated. V-MCM-41 catalysts containing 0.56–1.86 wt.% V have been prepared by incorporating the vanadium ions into the framework of mesoporous siliceous MCM-41, resulting in a highly ordered structure with large BET surface area and high su...

In this study MCM-41, Fe20-MCM-41 and Fe40-MCM-41 mesoporouse silicates have been prepared in various conditions with cetyltrimethylammonium bromide (C16) and dodecyltrimethyl-ammonium chloride as template and various mole ratios of Si/Fe. The resulted compositions have been characterized by power X-ray diffraction, N adsorption–desorption measurements and Fourier transform infrared spectroscop...

manganese (?) complex with 2, 2? bipyridine, 1, 1? dioxide (bpdo) ligand was immobilized within nanoreactors of mcm-41. the immobilized complex was characterized by powder x-ray diffraction (xrd), nitrogen adsorption desorption, and ftir. the pore volume, surface area and pore diameter of mcm-41 decreased after immobilization of mn complex. three bands observed at 1250, 1220 cm?1 and 757 cm?1 a...

In this study, an efficient and green process for the synthesis of dihydropyrimidin-2(1H)-ones from aromatic benzaldehydes, ethyl acetoacetate and urea using Al-MCM-41 as heterogeneous catalyst and microreactor under solvent-free conditions has been developed. The advantages of this method are easy work-up procedure, regeneration of the catalyst, clean and neutral reaction conditions.

In this study, an efficient and green process for the synthesis of dihydropyrimidin-2(1H)-ones from aromatic benzaldehydes, ethyl acetoacetate and urea using Al-MCM-41 as heterogeneous catalyst and microreactor under solvent-free conditions has been developed. The advantages of this method are easy work-up procedure, regeneration of the catalyst, clean and neutral reaction conditions.

Propylene is an important raw material for the production of many valuable compounds, especially polypropylene, consumption which continues to grow every year. The reaction oxidative dehydrogenation propane, where carbon dioxide used as a mild oxidant, promising method producing propylene. At same time, problem utilization greenhouse gas CO2 partially solved. synthesis and analysis physicochemi...