This article describes for the first time elaboration of a cationic exchange membrane (CEM) from an end-of-life reverse osmosis (RO) membrane. The has been prepared in two successive steps: (i) chlorine attack and (ii) filtration/adsorption polystyrene sulfonic acid (PSS) electrolyte solution. Physicochemical characterizations have undertaken including (Na+) transference number (t(Na+)), diffus...

Introduction: Proton exchange membrane (or polymer electrolyte membrane) fuel cells (PEMFCs) are attracting enormous research activities because they a new power source for applications in different industrial sectors, such as transportation, stationaries, and portable devices. Nafion is the available commercial material PEMs, but it has high production cost, leading to strong demand alternativ...

The transport properties and the swelling behaviour of NAFION and different sulfonated polyetherketones are explained in terms of distinct differences on the microstructures and in the pKa of the acidic functional groups. The less pronounced hydrophobic/hydrophilic separation of sulfonated polyetherketones compared to NAFION corresponds to narrower, less connected hydrophilic channels and to la...

The optical absorption, ionic conductivity, electronic conductivity, and gas separation properties have been evaluated for flexible composite films of ionically conductive polymers that contain partially embedded arrays of ordered, crystalline, p-type Si microwires. The cation exchange ionomer Nafion, and a recently developed anion exchange ionomer, poly(arylene ether sulfone) that contains qua...

In preparation for routine deployment in a network of greenhouse gas monitoring stations, we have designed and tested a simple method for drying ambient air to near or below 0.2 % (2000 ppm) mole fraction H2O using a Nafion dryer. The inlet system was designed for use with cavity ring-down spectrometer (CRDS) analyzers such as the Picarro model G2301 that measure H2O in addition to their princi...

Ionic polymer-metal composites (IPMCs) consist of a perfluorinated ionomer membrane (usually Nafion or Flemion). The ionomer is plated on both faces with a noble metal such as gold or platinum. It is neutralized with a certain amount of counterions that balance the electrical charge of anions covalently fixed to the backbone membrane. IPMCs are electroactive materials that can be used as actuat...

Proton exchange membrane fuel cells (PEMFCs) typically use Nafion®, which has many drawbacks, such as high cost, crossover, and strenuous synthesis processes. As such, an alternative Nafion®-ionomer free proton conductor drawn significant interest. Graphene oxide (GOM) is a promising due to its hydrophilic nature attractive conductivity under humidified conditions. However, pristine GOMs have i...

Abstract Synthesis of proton-conducting materials based on track-etched membranes from polyvinylidene fluoride and sulfonated cross-linked polystyrene is described. The synthesis has been carried out by filling the pores original or gamma-irradiated membrane copolymerization styrene/divinylbenzene followed sulfonation with chlorosulfonic acid. resulting have studied scanning electron microscopy...

We present an energetically autonomous robotic tadpole that uses a single membrane component for both electrical energy generation and propulsive actuation. The coupling of this small bio-inspired power source to a bio-inspired actuator demonstrates the first generation design for an energetically autonomous swimming robot consisting of a single membrane. An ionic polymer metal composite (IPMC)...

A new europium(III) membrane luminescent sensor based on a new tridentate bis(phosphinic acid)phosphine oxide (3) system has been developed. The synthesis of this new ligand is described and its full characterization by NMR, IR and elemental analyses is provided. The luminescent complex formed between europium(III) chloride and ligand 3 was evaluated in solution, observing that its spectroscopi...