Transition-metal dichalcogenides like molybdenum disulphide have attracted great interest as two-dimensional materials beyond graphene due to their unique electronic and optical properties. Solution-phase processes can be a viable method for producing printable single-layer chalcogenides. Molybdenum disulphide can be exfoliated into monolayer flakes using organolithium reduction chemistry; unfo...

The reagent 4-hydroxybenzaldehyde thiosemicarbazone (4-HBTS) has been used for the determination of Mo(VI) by spectrophotometric method. The reagent 4-HBTS gives green colour with Mo(VI) solution of weak acidic medium and the maximum absorbance was observed at 365nm, in acidic buffer p H 6.0. The molar absorptivity and Sandell’s sensitivity of Mo(VI)4-HBTS complex are 1.25 x 10 L mol cm and 0.0...

Double-layer composite coatings composed of a P2O5-based glass/Ca10(PO4)6(OH)2 (HA) mixture top layer and a simple HA underlayer, on Ti-6Al-4V substrates, were prepared using a plasma-spraying technique. The in vitro bioactivity of these coatings was assessed by immersion testing in simulated body fluid. Both scanning electron microscopy (SEM) analysis and the ionic solution changes followed by...

To elucidate plant mechanisms involved in molybdenum (Mo) sequestration and tolerance, Brassica spp. seedlings were supplied with molybdate, and the effects on plant physiology, morphology, and biochemistry were analyzed. When supplied with (colorless) molybdate Indian mustard (Brassica juncea) seedlings accumulated water-soluble blue crystals in their peripheral cell layers. Energy dispersive ...

A sequential injection system with dual analytical line was developed and applied in the comparison of two different detection systems viz; a conventional spectrophotometer with a commercial flow cell, and a multi-reflective flow cell coupled with a photometric detector under the same experimental conditions. The study was based on the spectrophotometric determination of phosphate using the mol...

The present paper describes a simple, selective and sensitive kinetic method for the determination of trace amounts of molybdenum(VI) based on its inhibitory effect on the reaction oxidation of 4-hydroxycoumarine by KMnO(4) in the presence of hydrochloric acid, at pH 1.75 at 25 degrees C. The rate of the indicator reaction was followed spectrophotometrically by measuring the decrease in the abs...