in current work a comprehensive mechanism based on intermediate radical termination theory is assumed for raft polymerization of styrene over cumyl dithiobenzoate as raft agent. rate constants for addition (ka) and fragmentation reactions (kf) are set to 6×106 and 5×104 respectively, which lead to an equilibrium constant value of k = ka/kf = 1.2 x 102. moment equations method was used to model ...

molecular dynamic simulation is a powerful method that monitors all variations in the atomic level in explicit solvent. by this method we can calculate many chemical and biochemical properties of large scale biological systems. in this work all-atom molecular dynamics simulation of polyalanine (pa) was investigated in the presence of 0.224, 0.448, 0.673, 0.897 and 1.122 m of guanidinium chlorid...

We use Atacama Large Millimeter/submillimeter Array CO(2-1) observations of six low-redshift Palomar-Green quasars to study the distribution and kinematics molecular gas their host galaxies at kpc-scale resolution. While content, fraction, star formation rates are similar those nearby massive, star-forming galaxies, quasar possess exceptionally compact, disky distributions with a median half-li...

Polystyrene (PSt) has been known as one of the important polymers with a wide range of applications. Ability to synthesize PSt with different but predictable molecular weights for various applications is very important in the laboratories and industries. In this study, using various simple and inexpensive techniques with only free radical mechanism, it was tried to synthesize PSt with different...