Inelastic neutron scattering (INS) is used to investigate a ZSM-5 catalyst that has been exposed to methanol vapour at elevated temperature. In-line mass spectrometric analysis of the catalyst exit stream confirms methanol-to-gasoline chemistry, whilst ex situ INS measurements detect hydrocarbon species formed in/on the catalyst during methanol conversion. These preliminary studies demonstrate ...

Polypropylene (PP) has been one of the most widely used polymers due to the versatility and cost benefits obtained with this material. In this work, composites of PP modified with nanostructured ZSM-5 zeolite were prepared and their thermal and mechanical properties were evaluated. Zeolites were synthetized by hydrothermal method and the crystallization time was modified to evaluate the effect ...

Highly b-oriented zeolite ZSM-5 films are critical for applications in catalysis and separations and may serve as models to study diffusion and catalytic properties in single zeolite channels. However, the introduction of catalytically active Al3+ usually disrupts the orientation of zeolite films. Herein, using structure-directing agents with hydroxy groups, we demonstrate a new method to prepa...

Molecular dynamics simulations have been carried out in order to investigate the adsorption and permeation phenomena of butane isomers through ZSM-5 membranes. Using the VT ensemble configurational-bias Monte Carlo technique, we are able to determine the preferred locations of the butane isomers in the ZSM-5 channels. In permeation simulations, using the VT ensemble non-equilibrium molecular dy...

Fe/ZSM-5 nanosheet zeolites of varying thickness were synthesized with di- and tetraquaternary ammonium structure directing agents and extensively characterized for their textural, structural, and catalytic properties. Introduction of Fe3+ ions in the framework of nanosheet zeolites was slightly less effective than in bulk ZSM-5 zeolite. Steaming was necessary to activate all catalysts for N2O ...