Superabsorbent polymer was prepared by graft polymerization of acrylic acid onto the chain of cellulose from flax shive by using potassium persulfate (KPS) as an initiator and N,N-methylenebisacrylamide (MBA) as a crosslinker under microwave irradiation. SEM photographs were also studied for more information about the shive, cellulose from shive, and the superabsorbent polymer. The structure of...

The present paper describes the synthesis and characterization of a new polymeric biomaterial mineralized with calcium phosphate using the reaction-diffusion method. The scaffold of this biomaterial was a hydrogel constituted by biocompatible polyethylene glycol methyl ether methacrylate (PEGMEM) and 2-(dimethylamino)ethyl methacrylate (DMAEM), which were cross-linked with N-N'-methylenebisacry...

BACKGROUND The interaction between biotin and avidin is utilized in a wide range of assay and diagnostic systems. A robust material capable of binding biotin should offer scope in the development of reusable assay materials and biosensor recognition elements. RESULTS Biotin-selective thin (3-5 nm) films have been fabricated on hexadecanethiol self assembled monolayer (SAM) coated Au/quartz re...

In this paper, we report an easy route for preparing new metal nanorod-polymer composites consisting of gold nanorods, Au NRs, and temperature responsive copolymer “microgel” particles. The microgel particles of ~200 nm in size, which contain carboxylic acid groups, were prepared by surfactant-free emulsion polymerization of a selected mixture made of N-isopropylacylamide and acrylic acid in th...

Thermoresponsive colloidal particles were prepared by seeded precipitation polymerization of N-isopropylacrylamide (NIPAM) in the presence of a crosslinking monomer, N,N-methylenebisacrylamide (MBA), using polystyrene latex particles (ca. 50 nm in diameter) as seeds in aqueous dispersion. Phase transitions of the prepared poly(N-isopropylacrylamide), PNIPAM, shells on polystyrene cores were stu...

Present study refers to the synthesis of new advanced materials based on poly(methacrylic acid) (PMAA) with previously reported own advanced modified clays by edge covalent bonding. This will create the premises to obtain nanocomposite hydrogels with combined hydrophilic-hydrophobic behavior absolutely necessary for co-delivery of polar/nonpolar substances. For the synthesis, N,N'-methylenebisa...

the objective of the present study is to develop and investigate the swelling behavior of ph-sensitive superporous hydrogel (sph) and sph composite (sphc). a novel superporous hydrogel containing poly (methacrylic acid-co-acrylamide) was synthesized from methacrylic acid and acrylamide through the aqueous solution polymerization, using n,n-methylenebisacrylamide as a crosslinker and ammonium pe...

Article history: Received March 26, 2013 Received in Revised form June 27, 2013 Accepted 28 June 2013 Available online 2 July 2013 A new durable antibacterial cotton fabric was successfully prepared by free-radical graft copolymerization of acrylic acid (AA) and itaconic acid (IA) onto a cotton fabric in an aqueous medium. Ammonium persulfate (APS) was used as the initiator in the presence of a...

   The objective of the present study is to develop and investigate the swelling behavior of pH-sensitive Superporous Hydrogel (SPH) and SPH composite (SPHC). A novel superporous hydrogel containing poly (methacrylic acid-co-acrylamide) was synthesized from methacrylic acid and acrylamide through the aqueous solution polymerization, using N,N-methylenebisacrylamide as a crosslinker and ammonium...