Materials with disordered structures have a crucial role in the rapid development of new technologies. Improvement of these materials for particular application, as well as preparation of novel composites is based on a thorough understanding of the basic mechanisms of charge carrier transport. Among various classes of structurally disordered materials, a family of iron phosphate glasses attract...

The crystallization of 40Fe2O3-60P2O5, 10ZnO-30Fe2O3-60P2O5 and (43.3−x)PbO–(13.7+x)Fe2O3–43P2O5, (0 < x < 30), glasses and glassceramic have been investigated. The structural evolution of glasses during heat treatment at various temperatures and the tendency for crystallization for series of glasses with modified composition are characterized by a dendrite-like phase separation in the early st...

Biogeochemical transformation (inclusive of dissolution) of iron (hydr)oxides resulting from dissimilatory reduction has a pronounced impact on the fate and transport of nutrients and contaminants in subsurface environments. Despite the reactivity noted for pristine (unreacted) minerals, iron (hydr)oxides within native environments will likely have a different reactivity owing in part to change...

The acquisition of iron from transferrin by Gram-negative bacterial pathogens is dependent on a periplasmic ferric-ion-binding protein, FbpA. FbpA shuttles iron from the outer membrane to an inner membrane transport complex. A bound phosphate anion completes the iron co-ordination shell of FbpA and kinetic studies demonstrate that the anion plays a critical role in iron binding and release in v...

aims: in the past few decades, more attention has been paid to clean up soils polluted with heavy metals by plants. a serious problem in this way is the amount of heavy metals uptake by plants. this study was conducted to evaluate the effectiveness of 3 local plants of mazandaran province, iran, in reducing and controlling the soil’s heavy metals. instrument & methods: the removal amount of thr...

he cost of sludge disposal can contribute significantly to the cost of product manufacturing. An opportunity exists to eliminate this cost of land disposal of sludge resulting from the zinc phosphate pretreatment process. In addition, the cost of the phosphating process may be reduced by reclaiming this sludge to a zinc-phosphate replenishment solution and other useful products. For those not f...

This study is comprised of the synthesis and characterization of uniform fine particles of iron oxide in different shapes and sizes. Varying amounts of iron (III) chloride and sodium dihydrogen phosphate was heated at 98 oC for various periods, following the forced hydrolysis method. Scanning electron microscopic analysis showed that the shape and size of the precipitated particl...

The influence of pH and aging upon the phosphate binding capacity of iron(II1) or aluminum hydroxides has been investigated. The formation of reactive polynuclear hydroxo complexes by the hydrolyzing cations and the subsequent oxolation process are starting points of a discussion of the observed influence of the experimental conditions upon the rate and extent of phosphate adsorption. The ratio...