We study the thickness of wetting layers in the binary-liquid mixture cyclohexane methanol. Far from the bulk critical point, the wetting layer thickness is independent of temperature, resulting from the competition between van der Waals and gravitational forces. Upon approaching the bulk critical temperature [t=(T(c)-T)/T(c)-->0], we observe that the wetting layer thickness diverges as t(-beta...

To approach this goal, we develop a detailed 1D model to describe the DMFC on the electrode and cell level, based on the in-house modeling framework DENIS. A two-phase flow model is implemented for the transport in gas diffusion layer (GDL) and catalyst layer (CL) at the anode side, whereas we consider only the gas phase at the cathode side. Electrochemistry is described by multistep mechanisms...

A novel heteroatoms (N, P, S and Fe) quaternary-doped carbon (HQDC-X, X refers to the pyrolysis temperature) can be fabricated by directly pyrolyzing a gram-negative bacteria, S. oneidensis MR-1 as precursors at 800 °C, 900 °C and 1000 °C under argon atmosphere. These HQDC-X catalysts maintain the cylindrical shape of bacteria after pyrolysis under high temperatures, while heteroatoms including...

Two randomized, single dose, 2-period, 2-sequence crossover studies were conducted to evaluate the comparative bioavailability of two clopidogrel formulations under fasting and fed conditions. Assessment of bioequivalence was based upon measurement of plasma concentrations of the parent drug, clopidogrel, and its major (inactive) metabolite, clopidogrel carboxylic acid, using improved methanol-...

For the last decade, dimethyl ether (DME) has been considered a promising alternative fuel for direct fuel cells because of several advantages over methanol. In this work, PtRu catalysts with a wide range of Pt-to-Ru ratios were screened for the direct DME fuel cell (DDMEFC) performance for the first time. Overall, Pt50Ru50 performs best in the high and middle voltage ranges, whereas Pt80Ru20 p...

The optimal location of sensors involves the selection of type, number and location of sensors from a set of available instruments with certain values of cost, precision and reliability. The optimal design not only satisfies economic criteria, but also some requirements on the quality of key variable estimates. In this work, a methodology for solving the sensor network design problem based on E...

We report on the analysis of the performance of each electrode of an air-breathing passive micro-direct methanol fuel cell (µDMFC) during polarization, stabilization and discharge, with CH3OH (2-20 M). A reference electrode with a microcapillary was used for separately measuring the anode the cathode potential. Information about the open circuit potential (OCP), the voltage and the mass transpo...

Direct methanol fuel cells (DMFCs) are promising electrochemical systems capable of producing electricity from the oxidation and reduction oxygen. In this work, effectiveness addition sulfuric acid as a supporting electrolyte for composition was assessed. The results showed that peak power curve in DMFCs with Pt/C cathode electrocatalysts increased progressively 70 mW cm−2 (0 mM H2SO4) to 115 c...

Performance decay of direct methanol fuel cells hinders technology competitiveness. The cathode electrochemical surface area loss is known to be a major reason for performance and it mainly affected by potential dynamics, locally influenced water crossover. To mitigate such phenomenon, novel materials components need developed intensively tested in relevant operating conditions. Thus, the devel...