A five-dimensional potential energy surface (PES) for the interaction of a rigid methane molecule with a rigid nitrogen molecule was determined from quantum-chemical ab initio calculations. The counterpoise-corrected supermolecular approach at the CCSD(T) level of theory was utilized to compute a total of 743 points on the PES. The interaction energies were calculated using basis sets of up to ...

Enteric methane emissions from beef cattle are a significant component of total greenhouse gas emissions from agriculture. The variation between beef cattle in methane emissions is partly genetic, whether measured as methane production, methane yield (methane production/DMI), or residual methane production (observed methane production - expected methane production), with heritabilities ranging ...

Methane-oxidizing bacteria (methanotrophs) attenuate methane emission from major sources, such as wetlands, rice paddies, and landfills, and constitute the only biological sink for atmospheric methane in upland soils. Their key enzyme is particulate methane monooxygenase (pMMO), which converts methane to methanol. It has long been believed that methane at the trace atmospheric mixing ratio of 1...

The presence of structure H (sH) methane hydrate in natural environments, in addition to the well-known structure-I (sI) and II (sII) hydrates, has recently been documented. Methane in the presence of condensates (C5-C7) forms sH hydrate at lower pressure than the sI hydrate. Thus, the occurrence of sH methane hydrate is likely to have both beneficial and negative practical implications. On the...

a dissolved methane sensor based on silicone tube was designed, constructed and optimized.the silicone tube diameter, silicone tube length and helium flow rate (as the carrier gas(were considered as process parameters to be optimized.a continuous stream of helium (50 ml/min) was directed through the tubing, sweeping out the dissolved methane which diffused through the walls of the tubing from t...

noncatalytic and nonoxidative conversion of methane in a dielectric barrier discharge (dbd) reactor is examined at different temperatures, gas residence times and input powers. in addition, the ratio of methane to helium as a diluant, is changed in the range of 0.6 to 1.8. results show significant synergetic effects of plasma, temperature and helium on the methane conversion and c2+ selectiviti...

Concentration of atmospheric methane is considered to have a significant effect on climate because of its GWP (Global Warming Potential), which is 21 times of CO2. Methane is generated by the process of methanogenesis under wet anaerobic conditions, oxidation by methanotrophic bacteria and transportation to the atmosphere. Wetlands are the major source of methane emission, because of the presen...

BACKGROUND Energy from remote methane reserves is transformative; however, unintended release of this potent greenhouse gas makes it imperative to convert methane efficiently into more readily transported biofuels. No pure microbial culture that grows on methane anaerobically has been isolated, despite that methane capture through anaerobic processes is more efficient than aerobic ones. RESUL...

adsorbed natural gas has various advantages and is relatively more economical than liquefaction and compression. carbon nanotubes can be introduced as a new candidate for natural gas storage. in this study, adsorption of methane was firstly studied on the as-prepared multi-walled carbon nanotubes, and then chemical and physical treatment of mwcnts was performed to enhance the methane adsorption...