a pvc membrane cr(iii) ion selective electrode has been constructed using 2h-1,4-benzothioazine-2,3(4h)dione dioxime (btd) as membrane carrier. the influence of membrane composition on the electroderesponse was studied. the electrode exhibits a nernstian response over a cr(iii) concentration range of 1.0 x10 6 to 1.0>< 10-1 m (r = 0.99) with a slope of 19.5 ± 0.5 mv per decade of concentration,...

This protocol describes the dynamic measurement of chloride ions using the transition time of a silver silver chloride (Ag/AgCl) electrode. Silver silver chloride electrode is used extensively for potentiometric measurement of chloride ions concentration in electrolyte. In this measurement, long-term and continuous monitoring is limited due to the inherent drift and the requirement of a stable ...

tea is the second most commonly consumed beverage world wide. tea ( camellia sinensis ) is a naturally rich source of fluoride. the quantity of fluoride intake is important in optimizing its dental caries-preventive role. intense concentration of fluoride in tea, can lead to excessive fluoride intake which may cause health problems in turn. the measurement of fluoride intake usually requires in...

Most P2-type layered oxides exhibit Na(+)/vacancy-ordered superstructures because of strong Na(+)-Na(+) interaction in the alkali metal layer and charge ordering in the transition metal layer. These superstructures evidenced by voltage plateaus in the electrochemical curves limit the Na(+) ion transport kinetics and cycle performance in rechargeable batteries. Here we show that such Na(+)/vacan...

2-amino-n-benzthioazolyl benzamide (abtb) was synthesized, characterized and used for thefabrication of a potentiometric sensor for cu2+ metal ions. the electrode exhibits linear response to cu(ii) over a wide concentration range (4.79×10 -8 – 1.85×10 -1 m) with nernstian slope of 30 ± 1.5 mvper decade. the electrode can be used in the ph range from 2 to 9. it has a fast response time of about1...

We have found that the specific capacity of a Li-intercalated metal-organic framework (iMOF) electrode material, 2,6-naphthalene dicarboxylate dilithium, can be increased by narrowing the distance between naphthalene layers via ordering. The increase in specific capacity can be attributed to formation of more efficient electron and ion pathways in the framework.

This contribution is devoted to explanation and prediction of corrosion pit propagation or stable pit growth, governed by ion transport properties in electrolytic solutions by deriving the (3D) mass balance for a body hosting a sharp dissolution front which separates the solid electrode from liquid electrolyte. The model is completed by Fick’s law of diffusion, governing the behavior of the dis...

The redox properties of sulfite ion has been examind using cyclic voltammetry in acetonitrile solvent at the surface of gold, pelatin and glassy carbon electrodes. It has bben found tha, sulfite ion exhibits two electron oxidation peak with EC’ mechanism. A novel chemically modified electrode containing Prussian blue complex and multi wall carbon nanotubes (MWCNs) was achieved on the surface of...