The Diels–Alder reaction kinetics between diphenylfulvene and maleimide using mechanochemistry in liquid state is described. This was carried out solid a modified vibratory ball-mill with temperature control solution toluene as solvent. effect of temperature, ball mass, material, additives, aging were studied. We reported for the first time mechanochemical depending on ratio mass/mass reagent. ...

The intensification of leaching of gold from a waste using mechanical activation (milling in water) and mechanochemical activation (milling in thiourea solution) were studied as the pretreatment steps. The leaching of “as-received“ sample in an acid thiourea solution resulted in 78 % Au dissolution, after mechanical activation 98 % and mechanochemical activation up to 99 % of the gold was leach...

The pseudo-five-component reaction between β-dicarbonyl compounds (2 molecules), diamines and α-iodoketones (2 molecules), prepared in situ from aryl ketones, was performed efficiently under mechanochemical conditions involving high-speed vibration milling with a single zirconium oxide ball. This reaction afforded symmetrical frameworks containing two pyrrole or fused pyrrole units joined by a ...

The products of mechanical treatment are surface atoms or molecules, substances with a crystal structure different from their initial one (another polymorph, amorphous), point or linear defects, radicals and new chemical substances. It is often assumed, that to increase the yield of the products of a mechanical treatment, it is necessary to increase the treatment time and the mechanical power i...

Ball-milling and pestle and mortar grinding have emerged as powerful methods for the development of environmentally benign chemical transformations. Recently, the use of these mechanochemical techniques in asymmetric organocatalysis has increased. This review highlights the progress in asymmetric organocatalytic reactions assisted by mechanochemical techniques.