A series of 2-amino pyridine-3-carbinitrile derivatives incorporated coumarin moiety has developed via multicomponent condensation of 3-acetyl-2H-chromen-2-one, arylaldehydes, malononitrile and ammonium acetate utilizing Brønsted acidic ionic liquid, (4-sulfobutyl)tris(4-sulfophenyl)phosphonium hydrogen sulfate as catalyst under solvent-free conditions. Good yields, short reaction times, straig...

Liquid-liquid two-phase systems formed by a hydrophobic ionic liquid and water find several useful ways of application in analytical chemistry. One of the most important properties of such two-phase systems is the mutual solubility of the IL and water. Recent advancements on this subject have been reviewed. The solubility of ionic liquids in water is related to the standard Gibbs energies of th...

Waste streams from the incineration of metal-containing materials like such as computer processor boards and batteries may contain critical rare earth elements praseodymium. Data on solubility Pr compounds their distribution coefficients in supercritical CO2/ionic liquid two-phase systems are important to determine if an ionic liquid/supercritical CO2 approach is feasible toward recovery a part...

systematic studies on the vapor-liquid equilibria (vle) and conductometric properties of aqueous solutions of model surface-active ionic liquid 1-dodecyl-3-methylimidazolium bromide ([c12mim]br) are performed in the absence and presence of a large series of electrolytes in order to achieve a deeper understanding about the molecular mechanism behind the specific salt effect on the aggregation be...

n,n-diethylethanaminium-2-(sulfooxy) ethyl sulfate was synthesized and used as  an efficient, green, and recyclable catalyst and solvent for the nitration of aromatic compounds by nitric acid at 80oc

the aim of this study was to investigate the removal of toluene from air through nano-graphene modified by ionic liquid (ng-il). the batch adsorption experiments in glass bottle of gas chromatography equipped with flame ionization detector (gc-fid) were used. graphene ultrahigh-quality synthesized by substrate-free gas-phase method in a single step and graphene sheets were deposited with ionic-...

The previous study (Wang and Voth, J. Am. Chem. Soc. 2005, 127, 12192) has shown that the nonpolar alkyl cationic tail groups of ionic liquids can aggregate and form nanoscale spatial heterogeneity. To facilitate applications of ionic liquids under nonequilibrium conditions, it is of great interest to see how this spatial heterogeneity of ionic liquids changes when an external electric field is...

A simple, novel, efficient and three-component procedure for the synthesis of pyrimido[4,5-d]pyrimidine-2,4-dione derivatives by the reaction of 6-amino-1,3-dimethyluracil, aldehyde and 2-benzylisothiourea hydrochloride promoted by ionic liquid 1-butyl-3-methylimidazolium bromide ([BMIm]Br) under solvent-free conditions is reported. The presented method is benefited from operational simplicity...