A cobalt(II) derivative was used as a suitable ionophore for the preparation of a polymeric membrane nitrite-selective electrode. The electrode reveals a Nemstian behavior over a very wide NO2- ion concentration range (1.0 x 10(-6)-1.0 x 10(-1) M) and a very low detection limit (5.0 x 10(-7) M). The potentiometric response is independent of the pH of solution in the pH range 4.0-9.5. The electr...

Three-dimensional (3D) nanoporous architectures, possessing high surface area, massive pores, and excellent structural stability, are highly desirable for many applications including catalysts and electrode materials in lithium ion batteries. However, the preparation of such materials remains a major challenge. Here, we introduce a novel method, instant gelation, for the synthesis of such mater...

Sodium-ion batteries operating at ambient temperature hold great promise for use in grid energy storage owing to their significant cost advantages. However, challenges remain in the development of suitable electrode materials to enable long lifespan and high rate capability. Here we report a sodium super-ionic conductor structured electrode, sodium vanadium titanium phosphate, which delivers a ...

We have found that the specific capacity of a Li-intercalated metal-organic framework (iMOF) electrode material, 2,6-naphthalene dicarboxylate dilithium, can be increased by narrowing the distance between naphthalene layers via ordering. The increase in specific capacity can be attributed to formation of more efficient electron and ion pathways in the framework.

Potentiometric sensor based on commercial pencil graphite electrodes coated with polyaniline (PAni) composite with Eosin Y (EY) termed as PGE/PAni-EY have been developed for potentiometric determination of silver ion. The electrode exhibited linear response with Nernstian slope of 57.6±0.8 mV per decade within the range of 1.0×10 to 1.0×10 M with limit of detection 6.5×10 M silver ion. Fast and...

Nb2O5 nanosheets are successfully synthesized through a facile hydrothermal reaction and followed heating treatment in air. The structural characterization reveals that the thickness of these sheets is around 50 nm and the length of sheets is 500 ~ 800 nm. Such a unique two dimensional structure enables the nanosheet electrode with superior performance during the charge-discharge process, such ...

In the present study, we investigate the potentiometric behavior of Cu2+ carbon paste electrodes based on two mercapto compounds 2-Ethylmino-5-Mercapto-1,3,4-Thiadiazole (EAMT) and 2-Acetylamino-5-mercapto-1,3,4-thiadiazole (AAMT) self-assembled on gold nano-paricle (GNP) as ionophore. Then, the results obtained from the modified electrodes are compared. The self-assembled ionophores exhibit a ...

Co₃O₄ nanorods were prepared by a facile hydrothermal method. Eco-friendly deionized water rather than organic solvent was used as the hydrothermal media. The as-prepared Co₃O₄ nanorods are composed of many nanoparticles of 30-50 nm in diameter, forming a finger-like morphology. The Co₃O₄ electrode shows a specific capacitance of 265 F g-1 at 2 mV s-1 in a supercapacitor and delivers an initial...