this paper deals with the extraction of l-theanine containing aliquat 336 as a carrier and cyclohexane as solvent across bulk liquid membrane. the optimum operation condition are as follows: extraction time of 150 min, initial concentration of theanine in the feed phase is 1.8 g/l, the carrier concentration is 0.5 m, the ion of the receiving phase is 0.2 m nacl of na2hpo4-nah2po4 buffer solutio...

electrochemical aptamer-based sensors attract a lot of interest as useful methods because of their low cost, accuracy, sensitivity, and simplicity. an electro-active redox molecule comprises the main part of the electrochemical-based sensors. ferrocene is one of the most popular redox molecule used in biosensor fabrication. but, instability of ferrocenium ion in strong nucleophilic reagents and...

Time-resolved kinetic studies of silylene, SiH(2), generated by laser flash photolysis of 1-silacyclopent-3-ene and phenylsilane, have been carried out to obtain rate constants for its bimolecular reactions with methanol, ethanol, 1-propanol, 1-butanol, and 2-methyl-1-butanol. The reactions were studied in the gas phase over the pressure range 1-100 Torr in SF(6) bath gas, at room temperature. ...

The deposition of large amounts of energy in a molecule by XUV/X-ray photon absorption or fast-ion collision, triggers a set of complex ultrafast electronic and nuclear dynamics that allow a deep understanding and control of chemical reactivity. This themed issue showcases the research performed in the understanding, monitoring and control of these processes.

in order to represent the potential energy function over the whole range of r, many potentialenergy functions have been proposed. in the present paper, we employ many potential energyfunctions, to use numerov method for solving the nuclear schrödinger equation for the ifmolecule, as an example of a heteronuclear diatomic molecules. then we determine thespectroscopic constants eω , e e x ω , e b...

vapor-liquid equilibrium in nh3-co2-h2o system at high pressures has been studied. the uniquac-nrf model for this system was extended by using the goppert 4 maurer reported datas. since the system contains molecules and ionic species the binary interaction parameters considered, where those are of molecule-molecule, molecule-ion and ion-ion types. these interaction parameters are taken as const...

In this paper, we report how graph theory can be used to analyze an ensemble of independent molecular trajectories, which react during the simulation time-length, and obtain structural kinetic information. This method is totally general here applied prototypical case gas phase fragmentation protonated cyclo-di-glycine. methodology allows us whole set trajectories in automatic computer-based way...

The acidity constants of some amino acids (Am) were determined by potentiometric pH titration. The stability constants of the 1:1 complexes formed between M2+: Ca2+, Mg2+, Mn2+, Co2+, Ni2+, Cu2+ or Zn2+ and Am2-, were determined by potentiometric pH titration in aqueous solution (I = 0.1 M, NaNO3, 25°C). The order of the stability constants was reported. It is shown that the stability of the bi...

The acidity constants of some amino acids (Am) were determined by potentiometric pH titration. The stability constants of the 1:1 complexes formed between M2+: Ca2+, Mg2+, Mn2+, Co2+, Ni2+, Cu2+ or Zn2+ and Am2-, were determined by potentiometric pH titration in aqueous solution (I = 0.1 M, NaNO3, 25°C). The order of the stability constants was reported. It is shown that the stability of the bi...