The IR and Raman spectra of the compounds (CH,),Sb-Sb(CH,), (I), [(CH,),Si],SbSb[Si(CH,),], (II), [(CH,),Si],As-As[Si(CH,),], (III) and (C,H,),Sb--Sb(C,H,), (IV) have been studied in the liauid and solid states. Given assianments for I to III are based on normal coordinate analyses, and force constants are reported. The solid state Raman spectra of I and II exhibit strong lines near 50 cm-‘, wh...

Single-molecule force spectroscopy is a powerful experimental technique for probing intermolecular forces and conformational transitions of individual molecules. This technique involves measuring the mechanical response of a molecule subjected to a constant or time-varying force. Statistical mechanics has played a pivotal role in interpreting forcemeasurements in terms of the underlying kinetic...

The effect of filling nanotubes with C60, CH4, or Ne on the mechanical properties of the nanotubes is examined. The approach is classical molecular dynamics using the reactive empirical bond order (REBO) and the adaptive intermolecular REBO potentials. The simulations predict that the buckling force of filled nanotubes can be larger than that of empty nanotubes, and the magnitude of the increas...

The Doi kinetic theory for homogeneous flows of rodlike liquid crystalline polymers (LCPs) is extended to inhomogeneous flows through introducing a nonlocal intermolecular potential. An extra term in the form of an elastic body force comes out as a result of this extension. Systematic asympototic analysis in the small Deborah number limit is carried out, and the classical EricksenLeslie equatio...

The spatial distribution of intermolecular forces governs macromolecular interactions. The atomic force microscope, a relatively new tool for investigating interaction forces between nanometer-scale objects, can be used to produce spatially resolved maps of the surface or material properties of a sample; these include charge density, adhesion and stiffness, as well as the force required to brea...

Using frictional force microscopy (FFM), the friction surface characteristics were compared between twisted nematic (TN) mode and vertical alignment (VA) mode alignment films (AFs). The friction asymmetry was detected depending on temperature conditions on TN mode AF, but not on VA mode AF. The difference between two modes was explained by leaning intermolecular repulsion caused by the pre-tilt...

The thermal denaturation of adenosine deaminase (ADA) has been investigated in the presence of sodium n-dodecyl sulphate (SDS) over the temperature range of (293-363K) in 2.5 mM phosphate buffer, pH 6.4 by temperature scanning spectroscopy. The interaction of SDS caused the folding of adenosine deaminanse resulting in a decrease of TH (temperature of minimum solubility), TS<...

the thermal denaturation of adenosine deaminase (ada) has been investigated in the presence of sodium n-dodecyl sulphate (sds) over the temperature range of (293-363k) in 2.5 mm phosphate buffer, ph 6.4 by temperature scanning spectroscopy. the interaction of sds caused the folding of adenosine deaminanse resulting in a decrease of th (temperature of minimum solubility), ts (temperature of maxi...

this paper studies pull-in behavior of a bio-mass sensor with a cantilevered cnt actuated electrostatically considering rippling deformation. although this phenomenon can change the behavior of cnt remarkably, its effect on the performance of a cnt-based mass sensor is not investigated yet. this investigation is based on modified euler-bernoulli beam theory and rippling effect is entered the eq...

The interaction of human serum albumin with Ethyl 2-[2-(dimethylamino)-4-(4-nitrophenyl)- 1,3-thiazole-5-yl]-2-oxoacetate was investigated by using isothermal titration UV-visible spectrophotometry in tris-buffer, pH 7.4. According to these results, it was found that there are a set of 4 binding sites for this ligand on HSA with positive cooperativity in the binding process. This thiazole deriv...