X-ray scattering and interfacial tension measurements are used to demonstrate the formation of nanometer-thick aqueous films on aqueous bulk subphases from polymer-salt biphase mixtures. X-ray scattering determines a coupling constant that characterizes the coupled capillary wave fluctuations of the liquid-vapor and liquid-liquid interfaces of this thin film. These data also determine an effect...

Interfacial materials with special wettability have become a burgeoning research area in materials science in the past decade. The unique surface properties of materials and interfaces generated by biomimetic approaches can be leveraged to develop effective solutions to challenging environmental problems. This critical review presents the concept, mechanisms, and fabrication techniques of inter...

The properties of the fiber/matrix interface in composites have an influence on their overall performance. Common methods for studying the interface are micromechanical tests that load a single fiber/matrix interface to failure. Two popular tests are the microbond test [1] and the single-fiber, pull-out test [2]. In a microbond test a droplet of matrix is sheared off the fiber by pulling the fi...

Fluid mixing plays a fundamental role in many natural and engineered processes, including groundwater flows in porous media, enhanced oil recovery, and microfluidic lab-on-a-chip systems. Recent developments have explored the effect of viscosity contrast on mixing, suggesting that the unstable displacement of fluids with different viscosities, or viscous fingering, provides a powerful mechanism...

Nanoparticles assemble at the interface between two fluids into disordered, liquid-like arrays where the nanoparticles can diffuse laterally at the interface. Using nanoparticles dispersed in water and amine end-capped polymers in oil, nanoparticle surfactants are generated in situ at the interface overcoming the inherent weak forces governing the interfacial adsorption of nanoparticles. When t...

New bounds are derived on the e ective heat conductivity tensor for an anisotropic two-phase composite with interfacial surface resistance between phases. The new upper bound is given in terms of the two-point correlation function, component volume fractions and moment of inertia tensor for the surface of each heterogeneity. The new lower bound is given in terms of the interfacial surface area,...

Janus gold nanoparticles (JPs) of ∼4 nm-diameter half functionalized with 1-hexanethiol as a hydrophobic capping ligand exhibit significantly higher interfacial activity, reproducibility and rheological response when the other half is functionalized with 1,2-mercaptopropanediol (JPs-MPD) than with 2-(2-mercaptoethoxy)ethanol (JPs-MEE), both acting as hydrophilic capping ligands. The interfacial...

The influence of various electrolytes such as sulfate, nitrate, and chloride on CO-water mass transfer was investigated in this study. The results indicate that the enhancement in the CO-water volumetric masstransfer coefficient ranged from 1.5 to 4.7 times that of a baseline system without electrolytes, depending on electrolyte type and concentration. For those electrolytes with the same anion...

Process intensification (PI) technologies such as rotating packed beds (RPBs) could reduce the size of absorber used in post-combustion CO2 capture (PCC) based on chemical absorption processes by about 12 times compared to absorber with standard packed beds. However, mass transfer correlations for predicting effective interfacial area and liquid film mass transfer coefficient in RPBs are limite...