The efficient segregation of water-soluble, acid-functionalized, single-walled carbon nanotubes (SWCNTs) at the oil/water interface was induced by dissolving low-molecular-weight amine-terminated polystyrene (PS-NH2) in the oil phase. Salt-bridge interactions between carboxylic acid groups of SWCNTs and amine groups of PS drove the assembly of SWCNTs at the interface, monitored by pendant drop ...

We investigated the effects of resveratrol (RES) on the oxidative stability of emulsions composed of stripped corn oil, acidic water and Tween 20 and determined its distribution in the intact emulsions by employing a well-established kinetic method. The distribution of RES is described by two partition constants, that between the oil-interfacial region, PO(I), and that between the aqueous and i...

This chapter covers selected fundamental topics in Materials Science, with the purpose of introducing certain concepts that will serve as a foundation for other chapters in this volume. The topics addressed include: interfacial Gibbsian thermodynamics, with special emphasis on adsorption (or interfacial segregation) phenomena; statistical thermodynamic treatments of interfacial segregation, wit...

Outer membrane phospholipase A (OMPLA) is an integral membrane enzyme that hydrolyses phospholipids requiring Ca(2+) as cofactor. In vitro studies have shown that OMPLA is only active as a dimer. The structures of monomeric and dimeric OMPLA provided possible clues to the activation process. In the inhibited dimeric species calcium ions are located at the dimer interface ideally suited to stabi...

When particles adsorb at a fluid/fluid interface at a sufficiently high concentration, the interface loses mobility and displays solidlike characteristics, a phenomenon called "interfacial jamming". Jamming can arrest interfacial tension-driven morphological coarsening in liquid/liquid or gas/liquid systems and therefore stabilize two phase morphologies with unusual interfacial shapes, for exam...

In this work, total smooth air-water interfacial areas were measured for a series of nine natural and model sandy porous media as a function of water saturation using synchrotron X-ray microtomography. Interfacial areas decreased linearly with water satuation, while the estimated maximum interfacial area compared favorably to the media geometric surface areas. Importantly, relative interfacial ...