Cyclic voltammograms of the aqueous solution containing polyammonium cations and the [Fe(CN)6]4-. anion at a plastic-formed carbon or platinum electrode were recorded. Polyammonium salts comprising quaternary ammonium in the main chain or sub chain and those comprising primary ammonium were tested. Under certain conditions, well-developed anodic and cathodic peak currents with the midpoint pote...

A simple, direct semi-micro method has been developed for serum iron and latent iron-binding capacity. For total serum iron, into a one cm cuvet are pipetted (a ) 1.5 ml of Na acetate buffer (pH 4.5) containing Na ascorbate and (b ) 0.3 ml of serum. The serum blank absorbance is measured at 562 nm, and 0.2 ml of ferrozine color reagent is added. After incubation (42°, 20 min), the absorbance is...

The dinuclear title compound, [Fe(2)(C(2)H(4)S(2))(C(24)H(20)OP(2))(CO)(5)] or (μ-SCH(2)CH(2)S-μ)Fe(2)(CO)(5)[Ph(2)PP(O)Ph(2)], con-tains a butterfly-shaped Fe(2)S(2) core in which the Fe⋯Fe separation is 2.5275 (6) Å. One of the Fe atoms is also coordinated to three carbonyl ligands and the other to two carbonyl ligands and one phosphane ligand [Ph(2)PP(O)Ph(2)]. Both Fe-atom geometries could ...

The effects of nickel, cobalt, chromium and zinc on the content of vitamins A, E and C, malondialdehyde (MDA), chlorophyll and carotenoids were investigated in bean seedlings (Phaseolus vulgaris L.) grown in Hoagland solution Control and heavy metal-treated plants were grown for ten days in Hoagland solution. Vitamin A, E, and C content were measured in primary leaves by high performance liquid...

The effects of lead, copper, cadmium and mercury on the content of chlorophyll, proline, retinol, α-tocopherol and ascorbic acid were investigated in 17-day-old bean seedlings (Phaseolus vulgaris L.) grown in Hoagland solution spiked with various concentrations of Pb, Cu, Cd and Hg. Control and heavy metal-treated plants were grown for 10 days in Hoagland solution. Content of total chlorophyll ...

Proof of concept was obtained that Fe(0) can stoichiometrically reduce nitrate to ammonium and that cathodic hydrogen [produced during anaerobic Fe(0) corrosion by water] can sustain microbial denitrification to reduce nitrate to more innocuous products (i.e., N2O and N2). Autotrophic, denitrifying growth on Fe(0) was proven through the use of a dual-flask apparatus. Cathodic H2 from a flask co...

In our study a new Fe-modified nano porous of MCM-41 was synthezied hydrothermally with cetyltrimethylammoniumbromide (C16TAB) as surfactant and charactrizied using XRD, SEM, FT-IR and BET. This work reports the adsorption of Neodymium from aqueous solution onto Fe-MCM-41.100 ml of stock solution of Neodymium was prepared.Various factors such as pH,the amount of adsorbent were considered. T...

The mechanism of green rust sulfate (GR-SO(4)) formation was determined using a novel in situ approach combining time-resolved synchrotron-based wide-angle X-ray scattering (WAXS) with highly controlled chemical synthesis and electrochemical (i.e., Eh and pH) monitoring of the reaction. Using this approach,GR-SO(4) was synthesized under strictly anaerobic conditions by coprecipitation from solu...

The decomposition of organometallic compounds as precursors has revolutionized the synthesis of nanoparticles in solution. However, effective control of size and size distribution of iron nanoparticles has remained challenging due to the high reactivity of iron towards oxygen or oxygen-containing materials. Reported is a decomposition study that shows how metal to ligand bonding and symmetry of...